(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2R,2'R,3R,3'R)-Bis-BIDIME|15-6240|1884680-48-1

(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzo[d][1,3]oxaphosphole, 97% (>99% ee) (2R,2'R,3R,3'R)-Bis-BIDIME

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Product Information

Product Name
(2R,2'R,3R,3'R)-3,3'-Di-tert-butyl-4,4'-bis(2,6-dimethoxyphenyl)-2,2',3,3'-tetrahydro-2,2'-bibenzod1,3oxaphosphole, 97% (>99% ee) (2R,2'R,3R,3'R)-Bis-BIDIME
Brand Name
US-Strem
Product Number
15-6240
CAS
1884680-48-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
138319716
IUPAC Name
(2R,3R)-3-tert-butyl-2-(2R,3R)-3-tert-butyl-4-(2,6-dimethoxyphenyl)-2H-1,3-benzoxaphosphol-2-yl-4-(2,6-dimethoxyphenyl)-2H-1,3-benzoxaphosphole
InChI Key
OXORIUANWLCHSQ-MNZXOXKBSA-N
SMILES
CC(C)(C)P@1C@@H(OC2=CC=CC(=C21)C3=C(C=CC=C3OC)OC)C@@H4OC5=CC=CC(=C5P@4C(C)(C)C)C6=C(C=CC=C6OC)OC

Application

Technical Notes:
1. Ligand/Rhodium catalyst for asymmetric hydrogenation of enamides.
2. Ligand/Rhodium catalyst for asymmetric arylboronic reagents addition to aryl ketone
References:
1. Angew. Chem., Int. Ed. 2013, 52, 4235.
2.Angew. Chem., Int. Ed. 2016, 55, 4527.
3.Adv. Syn. Cat. 2013, 355, 1297 .