(2S,3S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (S,S)-Me-BI-DIME|15-6220|1373432-11-1

(2S,3S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (S,S)-Me-BI-DIME

$747.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-6220_500_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(2S,3S)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2-methyl-2,3-dihydrobenzod1,3oxaphosphole, min. 97% (S,S)-Me-BI-DIME
Brand Name
US-Strem
Product Number
15-6220
CAS
1373432-11-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
59052746
IUPAC Name
(2S,3S)-3-tert-butyl-4-(2,6-dimethoxyphenyl)-2-methyl-2H-1,3-benzoxaphosphole
InChI Key
MWVWXQBMRNEOBK-RKNYENMMSA-N
SMILES
CC@H1OC2=CC=CC(=C2P@@1C(C)(C)C)C3=C(C=CC=C3OC)OC

Application

Technical Notes:
1. Ligand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions
References:
1.Org. Lett. 2012, 14 , 2258- -2261
2.J. Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148

References Data Source From Pubchem

Enantioselective Arylation of Oxindoles Using Modified BI-DIME Ligands
Publication Name: Synthesis
Publication Date: 2018-06-28
DOI: 10.1055/s-0036-1591590

Addressing the Challenges in Suzuki–Miyaura Cross-Couplings by Ligand Design
Publication Name: Synlett
Publication Date: 2016-06-23
DOI: 10.1055/s-0035-1562360

Search for Ideal P-Chiral Phosphorus Ligands for Practical Asymmetric Hydrogenation and Asymmetric Suzuki–Miyaura Coupling
Publication Name: Synlett
Publication Date: 2013-09-23
DOI: 10.1055/s-0033-1339875