(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (R)-BI-DIME|15-6211|1338454-03-7

(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzo[d][1,3]oxaphosphole, min. 97% (R)-BI-DIME

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Sku SC15-6211_2_G
US-Strem
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Product Information

Product Name
(R)-3-(t-Butyl)-4-(2,6-dimethoxyphenyl)-2,3-dihydrobenzod1,3oxaphosphole, min. 97% (R)-BI-DIME
Brand Name
US-Strem
Product Number
15-6211
CAS
1338454-03-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
89586662
IUPAC Name
(3R)-3-tert-butyl-4-(2,6-dimethoxyphenyl)-2H-1,3-benzoxaphosphole
InChI Key
BWPDUHMFZCEKIP-QHCPKHFHSA-N
SMILES
CC(C)(C)P@1COC2=CC=CC(=C21)C3=C(C=CC=C3OC)OC

Application

Technical Notes:
1L igand/palladium catalyst for asymmetric Suzuki-Miyaura cross-coupling reactions. L igand/nickeI catalyst for asymmetric intramolecular reductive cyclization
2.L igand/rhodium catalyst for asymmetric hydroboration
References:
1Org. Lett. 2012, 14 , 2258- 2261
2J.Am. Chem. Soc., 2014, 136, 570- 573
3.Angew. Chem., Int. Ed. 2015, 54, 7144-7148
4.Angew. Chem., Int. Ed. 2015, 54, 2520 -2524 5.Org. Chem. Front. 2015, 2, 1322-1325
6.J.Am.Chem. Soc. 2015, 137, 6746 6749

References Data Source From Pubchem

Palladium-Catalyzed α-Arylation of Sterically Hindered Indanones
Publication Name: Synfacts
Publication Date: 2018-10-18
DOI: 10.1055/s-0037-1611293

Stereoselective Synthesis of Tetrahydrofuran Lignans
Publication Name: Synthesis
Publication Date: 2018-10-02
DOI: 10.1055/s-0037-1610289

Palladium-Catalyzed Synthesis of Chiral-at-Cage Carboranes
Publication Name: Synfacts
Publication Date: 2018-05-17
DOI: 10.1055/s-0037-1609760

Palladium-Catalyzed Enantioselective Synthesis of 3,4-Dihydroquinolin-2-ones
Publication Name: Synfacts
Publication Date: 2018-02-15
DOI: 10.1055/s-0037-1609257