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Sku SC15-5715_5_G
US-Strem
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Product Information

Product Name
4-((1R,3R,5S,7R)-1,3,5-Triaza-7-phosphaadamantan-1-ium-1-yl)butane-1-sulfonate, min. 98%, PTABS
Brand Name
US-Strem
Product Number
15-5715
CAS
1430837-91-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
145711616
IUPAC Name
4-(3,5-diaza-1-azonia-7-phosphatricyclo3.3.1.13,7decan-1-yl)butane-1-sulfonate
InChI Key
KGJWBSOVUYDJAT-UHFFFAOYSA-N
SMILES
C1N2CN+3(CN1CP(C2)C3)CCCCS(=O)(=O)O-

Application

Technical Notes:
1.L igand for the low temperature thioetherification of chloro(hetero )arenes.8
2.L igand used in the efficient Pd catalyzed C-H (hetero )arylation of 1,3,4-0xadiazoles using
bromo(hetero )arenes.9
3.L igand used in the Pd catalyzed low temperature etherification of chloroheteroarenes.10
4.L igand used for the water soluble catalytic system for the Pd catalyzed amination of 6-chloropurine ribonucleoside and synthesis of alogliptin.1 1
5.L igand for the Pd catalyzed room temperature amination of heteroarenes .12
6.Versatile L igand for Suzuki-Miyaura, Sonogashira and Heck Reactions of Nucleosides.1 3
7.Ligand for the for the aminocarbonylation of nucleosides
8.L igand for the modification of Nucleosides and Heteroarenes.1,6
References:
1.Chem. Rec. 2021 21188-203
2.Curr. Protoc. Nucleic Acid Chem. 2020. 83. e117.
3.Synthesis PSP 2020.52 3595-3603
4.New J Chem 2020 14744-147 54.

References Data Source From Pubchem

C—N Bond-Forming Reactions Involving Primary Alkylamines and Cyclic Secondary Alkylamines

Publication Name: Science of Synthesis
Publication Date: 2022