(11bR)-N,N-Dimethyl-2,6-diphenyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%|15-5620|936010-61-6

(11bR)-N,N-Dimethyl-2,6-diphenyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%

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Sku SC15-5620_50_MG
US-Strem
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Product Information

Product Name
(11bR)-N,N-Dimethyl-2,6-diphenyl-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin-4-amine, 98%
Brand Name
US-Strem
Product Number
15-5620
CAS
936010-61-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
15474807
IUPAC Name
N,N-dimethyl-10,16-diphenyl-12,14-dioxa-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine
InChI Key
AHZJWCMLBZSNSW-UHFFFAOYSA-N
SMILES
CN(C)P1OC2=C(C3=CC=CC=C3C=C2C4=CC=CC=C4)C5=C(O1)C(=CC6=CC=CC=C65)C7=CC=CC=C7

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes
1.L igand for the Rh-catalyzed asymmetric intermolecular hydroacylation reaction with salicylaldehydes .
2.L igand for the enantioselective Co-catalyzed 6+2 cycloadditions of cycloheptatriene with alkynes .
3.Ligand used for the Ni-catalyzed enantio- and diastereos elective three-component coupling of 1 ,3-dienes, aldehydes, and a silylborane leading to a-chiral allylsilanes.
References:
1.Adv. Synth. Catal. 2007, 349, 11 85.
2.Adv. Synth. Catal. 2008, 350, 280.
3.Angew. Chem. Int. Ed. 2012, 51,1228.
4.Org. Biomol. Chem., 2014, 12, 2745.

References Data Source From Pubchem

Asymmetric Copper-Catalyzed C(sp)–H Bond Insertion of Carbenoids Derived from N-Tosylhydrazones
Publication Name: Synlett
Publication Date: 2018-09-14
DOI: 10.1055/s-0037-1611003