(11bR)-N,N-Dimethyl-2,6-diphenyl-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%

Technical Notes
1.L igand for the Rh-catalyzed asymmetric intermolecular hydroacylation reaction with salicylaldehydes .
2.L igand for the enantioselective Co-catalyzed [6+2] cycloadditions of cycloheptatriene with alkynes .
3.Ligand used for the Ni-catalyzed enantio- and diastereos elective three-component coupling of 1 ,3-dienes, aldehydes, and a silylborane leading to a-chiral allylsilanes.
References:
1.Adv. Synth. Catal. 2007, 349, 11 85.
2.Adv. Synth. Catal. 2008, 350, 280.
3.Angew. Chem. Int. Ed. 2012, 51,1228.
4.Org. Biomol. Chem., 2014, 12, 2745.