(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%, (99% ee)|15-5618|497883-22-4

(11bS)-N,N-Bis[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%, (99% ee)

$135.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-5618_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(11bS)-N,N-Bis(R)-1-phenylethyl-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin-4-amine, 98%, (99% ee)
Brand Name
US-Strem
Product Number
15-5618
CAS
497883-22-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
23592741
IUPAC Name
N,N-bis(1-phenylethyl)-12,14-dioxa-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine
InChI Key
LKZPDRCMCSBQFN-UHFFFAOYSA-N
SMILES
CC(C1=CC=CC=C1)N(C(C)C2=CC=CC=C2)P3OC4=C(C5=CC=CC=C5C=C4)C6=C(O3)C=CC7=CC=CC=C76

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes:
1.Cyclization - Enantioselective cyclization of aromatic ketimines containing alkenyl groups tethered at the meta position of an imine directing group has been achieved using 5 mol% RhCl(coe)22 and 15 mol % of this (S)-BINOL -derived phos phoramidite ligand .
References:
1. J. Am. Chem. Soc., 2004, 126, 7192-7193.

References Data Source From Pubchem

Transition-Metal-Catalyzed Nucleophilic Dearomatization of Electron-Deficient Heteroarenes
Publication Name: Synthesis
Publication Date: 2021-09-09
DOI: 10.1055/a-1577-7638

Synthesis of 2-Methylindoline- and 2-Methyl-1,2,3,4-tetrahydroquinoline-Derived Phosphoramidites and Their Applications in Iridium-Catalyzed Allylic Alkylation of Indoles
Publication Name: Synthesis
Publication Date: 2009-05-19
DOI: 10.1055/s-0029-1216823

In Pursuit of an Ideal Carbon–Carbon Bond-Forming Reaction: Development and Applications of the Hydrovinylation of Olefins
Publication Name: Synlett : accounts and rapid communications in synthetic organic chemistry
Publication Date: 2009-03-16
DOI: 10.1055/s-0028-1088213