(11bR)-N-Methyl-N-[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%|15-5610|1021439-57-5

(11bR)-N-Methyl-N-[(R)-1-phenylethyl]-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin-4-amine, 98%

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Sku SC15-5610_50_MG
US-Strem
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Product Information

Product Name
(11bR)-N-Methyl-N-(R)-1-phenylethyl-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin-4-amine, 98%
Brand Name
US-Strem
Product Number
15-5610
CAS
1021439-57-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
86337213
IUPAC Name
N-methyl-N-(1R)-1-phenylethyl-12,14-dioxa-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-13-amine
InChI Key
WZQUIEYZCMZJOB-HXUWFJFHSA-N
SMILES
CC@H(C1=CC=CC=C1)N(C)P2OC3=C(C4=CC=CC=C4C=C3)C5=C(O2)C=CC6=CC=CC=C65

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes
1Ligand for the Ni-catalyzed for asymmetric hydrovinylation of vinylarenes and acylic 1 ,3-dienes.
2.Ligand for the enantioselective Co-catalyzed 6+2 cycloadditions of cycloheptatriene with alkynes .
References:
1.Org. L ett.2008, 10, 1657.
2.Adv. Synth. Catal. 2008, 350, 280.