1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh|15-5355|97739-46-3

1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh

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Sku SC15-5355_500_MG
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Product Information

Product Name
1,3,5,7-Tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphaadamantane, 99% MeCgPPh
Brand Name
US-Strem
Product Number
15-5355
CAS
97739-46-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
53427790
IUPAC Name
1,3,5,7-tetramethyl-8-phenyl-2,4,6-trioxa-8-phosphatricyclo3.3.1.13,7decane
InChI Key
AVVSJWUWBATQBX-UHFFFAOYSA-N
SMILES
CC12CC3(OC(O1)(CC(O2)(P3C4=CC=CC=C4)C)C)C

Application

Technical Note:
1.A bulky, robust, and electron-poor ligand that gives efficient rhodium hydroformylation and palladium cross-coupling catalysts.
References:
1.Dalton Transactions, 2005, 6, 1079. 2.Synthesis., 2007, 23, 3722.
3.Tetrahedron L ett., 2004, 45, 8319.
4.J. Org. Chem, 2004, 69, 7635.

References Data Source From Pubchem

Synthesis, structures, and phototransformations of 3-acyl-2-hetarylchromones with nitroxide substituents
Publication Name: Russian Chemical Bulletin
Publication Date: 2024-11
DOI: 10.1007/s11172-024-4450-0

Synthesis of A-1331852
Publication Name: Synfacts
Publication Date: 2020-11-17
DOI: 10.1055/s-0040-1706390

Synthesis of ABBV-744
Publication Name: Synfacts
Publication Date: 2020-07-21
DOI: 10.1055/s-0040-1707095

An Efficient Palladium-Catalysed Aminocarbonylation of Benzyl Chlorides
Publication Name: Synlett
Publication Date: 2020-01-10
DOI: 10.1055/s-0039-1690786

Diastereoselective Pd-Catalyzed Aryl Cyanation and Aryl Borylation
Publication Name: Palladium and Nickel Catalyzed Transformations Forming Functionalized Heterocycles
Publication Date: 2020
DOI: 10.1007/978-3-030-54077-7_2