(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine, min. 97% CTH-(R)-Xylyl-P-PHOS

Technical Notes:
1Chiral ligand for ruthenium- catalyzed asymmetric hydrogenation of aromatic ketones.
2.Chiral ligand for iridium- catalyzed asymmetric hydrogenation of quinolines .
3.Chiral ligand for copper- catalyzed as ymmetric hydrosilylation of ketones.
4.Synthesis of new chiral 2-functionized-1 ,2,3,4-tetrahydroquinoline derivatives via as ymmetric hydrogenation of s ubstitutedquinolines
5.Rhodium-biphosphine-catalyzed as ymmetric, intermolecular hydroheteroarylation of a-substituted acrylate derivatives.
References:
1J. Organomet. Chem..2006, 691.2332.
2.Tetrahedron Asym.2007. 18, 2625. 3.Chem. Eur. J.. 2009. 15, 5888.
4.Tetrahedron, 2013, 69, 9322.
5. J. Am. Chem. Soc.. 2015, 137. 508.