(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine, min. 97% CTH-(R)-Xylyl-P-PHOS|15-5210|442905-33-1

(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine, min. 97% CTH-(R)-Xylyl-P-PHOS

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Product Information

Product Name
(R)-(+)-2,2',6,6'-Tetramethoxy-4,4'-bis(di(3,5-xylyl)phosphino)-3,3'-bipyridine, min. 97% CTH-(R)-Xylyl-P-PHOS
Brand Name
US-Strem
Product Number
15-5210
CAS
442905-33-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11182279
IUPAC Name
3-4-bis(3,5-dimethylphenyl)phosphanyl-2,6-dimethoxy-3-pyridinyl-2,6-dimethoxy-4-pyridinyl-bis(3,5-dimethylphenyl)phosphane
InChI Key
JRTHAKOHBMETRC-UHFFFAOYSA-N
SMILES
CC1=CC(=CC(=C1)P(C2=CC(=CC(=C2)C)C)C3=CC(=NC(=C3C4=C(N=C(C=C4P(C5=CC(=CC(=C5)C)C)C6=CC(=CC(=C6)C)C)OC)OC)OC)OC)C

Application

Technical Notes:
1Chiral ligand for ruthenium- catalyzed asymmetric hydrogenation of aromatic ketones.
2.Chiral ligand for iridium- catalyzed asymmetric hydrogenation of quinolines .
3.Chiral ligand for copper- catalyzed as ymmetric hydrosilylation of ketones.
4.Synthesis of new chiral 2-functionized-1 ,2,3,4-tetrahydroquinoline derivatives via as ymmetric hydrogenation of s ubstitutedquinolines
5.Rhodium-biphosphine-catalyzed as ymmetric, intermolecular hydroheteroarylation of a-substituted acrylate derivatives.
References:
1J. Organomet. Chem..2006, 691.2332.
2.Tetrahedron Asym.2007. 18, 2625. 3.Chem. Eur. J.. 2009. 15, 5888.
4.Tetrahedron, 2013, 69, 9322.
5. J. Am. Chem. Soc.. 2015, 137. 508.

References Data Source From Pubchem

Advances in transition metal-catalyzed allylic substitution with unstabilized nucleophiles
Publication Name: Science China Chemistry
Publication Date: 2025-11-12
DOI: 10.1007/s11426-024-2611-2

Chelation enables selectivity control in enantioconvergent Suzuki–Miyaura cross-couplings on acyclic allylic systems
Publication Name: Nature Chemistry
Publication Date: 2024-02-08
DOI: 10.1038/s41557-023-01430-8

Chiral Metal Nanoparticles for Asymmetric Catalysis
Publication Name: Topics in Organometallic Chemistry
Publication Date: 2020
DOI: 10.1007/3418_2020_39

Asymmetric Synthesis Using Thioamides
Publication Name: Chemistry of Thioamides
Publication Date: 2019
DOI: 10.1007/978-981-13-7828-7_5

Palladium-Catalysed Construction of All-Carbon Quaternary Centres with Propargylic Electrophiles: Challenges in the Simultaneous Control of Regio-, Chemo- and Enantioselectivity
Publication Name: Synthesis
Publication Date: 2018-03-27
DOI: 10.1055/s-0036-1591957