(R)-(+)-7-[4(S)-(Benzyl)oxazol-2-yl]-7'-diphenylphosphino-2,2’,3,3’-tetrahydro-1,1’-spirobiindane, min. 97% (Ra,S)-Ph-Bn-SIPHOX|15-5186|2074610-05-0

(R)-(+)-7-[4(S)-(Benzyl)oxazol-2-yl]-7'-diphenylphosphino-2,2’,3,3’-tetrahydro-1,1’-spirobiindane, min. 97% (Ra,S)-Ph-Bn-SIPHOX

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Product Information

Product Name
(R)-(+)-7-4(S)-(Benzyl)oxazol-2-yl-7'-diphenylphosphino-2,2’,3,3’-tetrahydro-1,1’-spirobiindane, min. 97% (Ra,S)-Ph-Bn-SIPHOX
Brand Name
US-Strem
Product Number
15-5186
CAS
2074610-05-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
58232657
IUPAC Name
(3R)-4-(4S)-4-benzyl-4,5-dihydro-1,3-oxazol-2-yl-3,3'-spirobi1,2-dihydroindene-4'-yl-diphenylphosphane
InChI Key
WDIPXXMCRPGMIB-RUCSKDCOSA-N
SMILES
C1CC@@2(CCC3=C2C(=CC=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)C6=C1C=CC=C6C7=NC@H(CO7)CC8=CC=CC=C8

Application

Technical Notes :
1. Chiral ligands for the iridium-catalyzed, asymmetric hydrogenation of imines .
2.Chiral ligands for the iridium-catalyzed, asymmetric hydrogenation of a-ß unsaturated carboxylic acids. 3.Chiral ligands for iridium-catalyzed, asymmetric hydrogenation of a,-oxy-a,ß-unsaturated carboxylic acids.
References:
1.J. Am. Chem. Soc., 2006, 128, 12886.
2. J. Am. Chem. Soc..2008, 130, 8584.
3.J. Am. Chem. Soc., 2010, 132, 1172.