(11aS)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin, min. 97% (S)-SITCP|15-5185|885701-78-0

(11aS)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin, min. 97% (S)-SITCP

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Sku SC15-5185_100_MG
US-Strem
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Product Information

Product Name
(11aS)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno7,1-cd:1’,7’-efphosphocin, min. 97% (S)-SITCP
Brand Name
US-Strem
Product Number
15-5185
CAS
885701-78-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
92043569
IUPAC Name
18-phenyl-10-phosphapentacyclo10.6.1.11,4.016,19.08,20icosa-3,5,8(20),12,14,16(19)-hexaene
InChI Key
WNSOXOMTYBAEBG-UHFFFAOYSA-N
SMILES
C1C=CC2=CCC34C2=C1CPCC5=CC=CC(=C53)CC4C6=CC=CC=C6

Application

Technical Note:
1. Phosphine -catalyzed intra-and intermolecular gamma-addition of nitrogen nucleophiles to allenoates and alkynoates.
2.Catalytic asymmetric construction of the tryptanthrin skeleton via enantioselective decarboxylativo 4+2 cyclization.
3.Catalytic, enantioselective carbon-oxygen bond formation - phosphine-catalyzed synthesis of benzylic esters via oxidation of benzylic C-H bonds.
4.Use of a new spirophosphine to achieve catalytic, enantios elective 4+ 1 annulations of amines with allenes to generatedihydropyrroles.
References:
1.Angew. Chem. Int. Ed.2013, 52, 2525. 2.Org. Lett.. 2017, 19, 3219
3.J. Am. Chem. Soc.. 2016, 138, 12069. 4.J. Am. Chem. Soc.. 2015, 137, 3803