(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin, min. 97% (R)-SITCP|15-5184|856407-37-9

(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno[7,1-cd:1’,7’-ef]phosphocin, min. 97% (R)-SITCP

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Sku SC15-5184_100_MG
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Product Information

Product Name
(11aR)-(+)-5,6,10,11,12,13-Hexahydro-5-phenyl-4H-diindeno7,1-cd:1’,7’-efphosphocin, min. 97% (R)-SITCP
Brand Name
US-Strem
Product Number
15-5184
CAS
856407-37-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11325691
IUPAC Name
10-phenyl-10-phosphapentacyclo10.6.1.11,4.016,19.08,20icosa-4(20),5,7,12,14,16(19)-hexaene
InChI Key
VAPJMVSYFGSRTG-UHFFFAOYSA-N
SMILES
C1CC23CCC4=C2C(=CC=C4)CP(CC5=CC=CC1=C35)C6=CC=CC=C6

Application

Technical Notes:
1.Chiral catalyst for the intra and intermolecular v addition of nitrogen nucleophiles to Y substituted alkynoates or allenoates. 2.Phosphine catalyzed ß ,v-umpolung domino reaction of allenic es ters: facile synthesis of tetrahydrobenzofuranones bearing a chiral tetrasubstituted stereogenic carbon center.
3.Phosphine catalyzed highly enantiose;ective 3 +3cycloaddition of Morita- B aylis -Hillman c arbonates with C,N-cyclic azomethine imines .
References :
1. Angew. Chom. Int. Ed.. 2013, 52,. 2525. 2.Angew. Chem. Int. Ed., 2015, 54, 1511. 3. J, Am. Chom. Soc, 2015, 137, 4316.

References Data Source From Pubchem

Alkylphosphonium Salts with a Chiral Binaphthyl Backbone
Publication Name: Science of Synthesis
Publication Date: 2022

Asymmetric Catalysis by Phosphines
Publication Name: Science of Synthesis
Publication Date: 2022

Asymmetric Palladium-Catalyzed Allylic C–H Functionalization
Publication Name: Synfacts
Publication Date: 2021-10-19
DOI: 10.1055/s-0040-1720672

Recent Advances in Visible-Light-Promoted Copper Catalysis in Organic Reactions
Publication Name: Synthesis
Publication Date: 2021-07-27
DOI: 10.1055/a-1533-3597

Recent Advances in the Construction of Quaternary Stereocenters via Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation
Publication Name: Synthesis
Publication Date: 2021-07-22
DOI: 10.1055/a-1533-3085