(S)-(-)-7,7'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-SDP|15-5175|528521-86-0

(S)-(-)-7,7'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-SDP

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Sku SC15-5175_100_MG
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Product Information

Product Name
(S)-(-)-7,7'-Bis(diphenylphosphino)-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 97% (S)-SDP
Brand Name
US-Strem
Product Number
15-5175
CAS
528521-86-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
12086160
IUPAC Name
(4'-diphenylphosphanyl-3,3'-spirobi1,2-dihydroindene-4-yl)-diphenylphosphane
InChI Key
DKZNVWNOOLQCMJ-UHFFFAOYSA-N
SMILES
C1CC2(CCC3=C2C(=CC=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)C6=C1C=CC=C6P(C7=CC=CC=C7)C8=CC=CC=C8

Application

Technical Notes:
1. L igands used for the ruthenium-catalyzed hydrogenation of simple and cyclic ketones with high activity and enantioselectivity.
2.Ligands used for palladium-catalyzed asymmetric allylic alkylations.
References:
1.J. Am. Chem. Soc., 2003, 125, 4404.
2.J.Org. Chem., 2005, 70, 2967.
3.Adv. Synth. Catal., 2004, 346, 625.

References Data Source From Pubchem

Construction of Quaternary Allylic Amino Acid Derivatives through Palladium-Catalyzed Allylic Alkylation Reaction of Azlactones with Vinyl Aziridine
Publication Name: Synthesis
Publication Date: 2022-07-27
DOI: 10.1055/a-1878-8084

Racemic α-Alkyl/Aryl-Substituted Ketones
Publication Name: Science of Synthesis
Publication Date: 2022

Racemic α-Amino/Amido-Substituted Ketones
Publication Name: Science of Synthesis
Publication Date: 2022

Racemic α-Alkoxy/Aryloxy-Substituted Ketones
Publication Name: Science of Synthesis
Publication Date: 2022

Recent Developments in Transition-Metal-Catalyzed Asymmetric Hydrogenation of Enamides
Publication Name: Synthesis
Publication Date: 2020-10-20
DOI: 10.1055/s-0040-1705939