(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP-3-Me|15-5158|1298133-36-4

(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-[(3-methylpyridine-2-ylmethyl)amino]-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP-3-Me

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Product Information

Product Name
(R)-(+)-7-Bis(3,5-di-t-butylphenyl)phosphino-7'-(3-methylpyridine-2-ylmethyl)amino-2,2',3,3'-tetrahydro-1,1'-spirobiindane, min. 98% (>99% ee) (R)-DTB-SpiroPAP-3-Me
Brand Name
US-Strem
Product Number
15-5158
CAS
1298133-36-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
54671426
IUPAC Name
(3R)-4'-bis(3,5-ditert-butylphenyl)phosphanyl-N-(3-methyl-2-pyridinyl)methyl-3,3'-spirobi1,2-dihydroindene-4-amine
InChI Key
XDNYVKUMWMLBJV-OIVUAWODSA-N
SMILES
CC1=C(N=CC=C1)CNC2=CC=CC3=C2C@@4(CC3)CCC5=C4C(=CC=C5)P(C6=CC(=CC(=C6)C(C)(C)C)C(C)(C)C)C7=CC(=CC(=C7)C(C)(C)C)C(C)(C)C

Application

Technical Notes:
1.Iridium/ligand catalyst for the highly efficient, as ymmetric hydrogenation of ß- aryl and ß-ketoesters . 2.Extremely efficient chiral iridium catalyst used for the asymmetric hydrogenation of ketones.
3.Iridium/ligand catalyst for the highly efficient, as ymmetric hydrogenation of ß-aryI and ß-ketoesters.
Reference:
1. Angew. Chem Int. Ed., 2011, 50, 7329. 2 Angew. Chem Int. Ed., 2012, 51, 201. 3. Org. Lett., 2012, 14, 6158.

References Data Source From Pubchem

Asymmetric Hydrogenation of Ketones
Publication Name: Science of Synthesis
Publication Date: 2015