(-)-1,13-Bis[di(4-methylphenyl)phosphino]-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene, 97% (S,S,S)-(-)-Tol-SKP|15-4331|1548897-80-8

(-)-1,13-Bis[di(4-methylphenyl)phosphino]-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano[3,2-d]xanthene, 97% (S,S,S)-(-)-Tol-SKP

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Product Information

Product Name
(-)-1,13-Bisdi(4-methylphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-1benzopyrano3,2-dxanthene, 97% (S,S,S)-(-)-Tol-SKP
Brand Name
US-Strem
Product Number
15-4331
CAS
1548897-80-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
118102349
IUPAC Name
(10S,14S)-20-bis(4-methylphenyl)phosphanyl-2,22-dioxapentacyclo12.8.0.01,10.03,8.016,21docosa-3(8),4,6,16(21),17,19-hexaen-4-yl-bis(4-methylphenyl)phosphane
InChI Key
QGOSBHUTQQGVPA-IMUOSOIKSA-N
SMILES
CC1=CC=C(C=C1)P(C2=CC=C(C=C2)C)C3=CC=CC4=C3OC56C@H(C4)CCCC@H5CC7=C(O6)C(=CC=C7)P(C8=CC=C(C=C8)C)C9=CC=C(C=C9)C

Application

Technical Note:
1. Efficient ligand for the Au(I)- catalyzed, highly stereoselective, olefin cyclopropanation of diazooxindoles.
Reference:
1.J. Am. Chem. Soc., 2013, 135, 8197.