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Sku SC15-4311_100_MG
US-Strem
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Product Information

Product Name
(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-1benzopyrano 3,2-dxanthene, 97% (S,S,S)-(-)-Ph-SKP
Brand Name
US-Strem
Product Number
15-4311
CAS
1439556-82-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71746686
IUPAC Name
(10S,14S)-20-diphenylphosphanyl-2,22-dioxapentacyclo12.8.0.01,10.03,8.016,21docosa-3(8),4,6,16(21),17,19-hexaen-4-yl-diphenylphosphane
InChI Key
RXNGOILZLRYHEN-CIKQOIAFSA-N
SMILES
C1CC@H2CC3=C(C(=CC=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)OC26C@@H(C1)CC7=C(O6)C(=CC=C7)P(C8=CC=CC=C8)C9=CC=CC=C9

Application

Technical Notes:
1. Efficient ligand for the Au(l)-catalyzed, highly stereoselective, olefin cyclopropanation of diazooxindoles.
2.Palladium-catalyzed asymmetric allylic amination of Morita- Baylis-Hilman adducts. Exceptionally high efficiency and newmechanism
3. See also 15-4320
References:
1.J. Am. Chem. Soc., 2013, 135, 8197. 2.J.Am Chem. Soc., 2014, 136, 405. 3. Angew. Chem.. Int. Ed. 2012, 51, 936.

References Data Source From Pubchem

Assembling Chiral Center of Heterocycles by Palladium-Catalyzed Asymmetric Hydrocarbonylation

Publication Name: Synlett
Publication Date: 2022-04-20
DOI: 10.1055/a-1796-2255

Recent Advances in Decarboxylative Conversions of Cyclic Carbonates and Beyond

Publication Name: Synthesis
Publication Date: 2022-02-15
DOI: 10.1055/a-1715-7413

Addition of Nitrogen Nucleophiles

Publication Name: Science of Synthesis
Publication Date: 2022

Rhodium-Catalyzed Hydrogenation of Enol Esters

Publication Name: Synfacts
Publication Date: 2018-02-15
DOI: 10.1055/s-0037-1609297

Palladium-Catalyzed Asymmetric Allylic Alkylation

Publication Name: Synfacts
Publication Date: 2017-06-19
DOI: 10.1055/s-0036-1590534