(-)-1,13-Bis(diphenyl)phosphino-(5aS,8aS,14aS)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene, 97% (S,S,S)-(-)-Ph-SKP

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Sku SC15-4311_100_MG
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General Details
CAS # 1439556-82-7
SMILES
Chemical Purity
Molecular Formula C44H38O2P2
Chemical Formula
Formula Weight 660.72
Reaction
Note
Physical Properties
Purity 97%
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1. Efficient ligand for the Au(l)-catalyzed, highly stereoselective, olefin cyclopropanation of diazooxindoles.
2.Palladium-catalyzed asymmetric allylic amination of Morita- Baylis-Hilman adducts. Exceptionally high efficiency and newmechanism
3. See also 15-4320
References:
1.J. Am. Chem. Soc., 2013, 135, 8197. 2.J.Am Chem. Soc., 2014, 136, 405. 3. Angew. Chem.. Int. Ed. 2012, 51, 936.