(+)-1,13-Bis(diphenyl)phosphino-(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene, 97% (R,R,R)-(+)-Ph-SKP|15-4310|1360823-43-3

(+)-1,13-Bis(diphenyl)phosphino-(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-[1]benzopyrano [3,2-d]xanthene, 97% (R,R,R)-(+)-Ph-SKP

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Sku SC15-4310_25_MG
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Product Information

Product Name
(+)-1,13-Bis(diphenyl)phosphino-(5aR,8aR,14aR)-5a,6,7,8,8a,9-hexahydro-5H-1benzopyrano 3,2-dxanthene, 97% (R,R,R)-(+)-Ph-SKP
Brand Name
US-Strem
Product Number
15-4310
CAS
1360823-43-3
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
78167834
IUPAC Name
(20-diphenylphosphanyl-2,22-dioxapentacyclo12.8.0.01,10.03,8.016,21docosa-3(8),4,6,16(21),17,19-hexaen-4-yl)-diphenylphosphane
InChI Key
RXNGOILZLRYHEN-UHFFFAOYSA-N
SMILES
C1CC2CC3=C(C(=CC=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)OC26C(C1)CC7=C(O6)C(=CC=C7)P(C8=CC=CC=C8)C9=CC=CC=C9

Application

Technical Notes:
1. Efficient ligand for the Au(l)-catalyzed, highly stereoselective, olefin cyclopropanation of diazooxindoles.
2.Palladium-catalyzed asymmetric allylic amination of Morita- Baylis-Hilman adducts. Exceptionally high efficiency and newmechanism
3. See also 15-4320
References:
1.J. Am. Chem. Soc., 2013, 135, 8197. 2.J.Am Chem. Soc., 2014, 136, 405. 3. Angew. Chem.. Int. Ed. 2012, 51, 936.