(11bR)-4-Hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)

Name: (11bR)-4-Hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee) | 695162-87-9
Brand: US-Strem
SKU: SC15-3712_50_MG
Price: 182.0 USD
Availability: InStock

$182.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.

Sku SC15-3712_50_MG

Vendor: US-Strem

Product Information

Product Name

(11bR)-4-Hydroxy-2,6-bis(2,4,6-trimethylphenyl)-4-oxide-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 98%, (99% ee)

Brand Name

US-Strem

Product Number

15-3712

CAS

695162-87-9

Certificate of Analysis (COA)

COA not found

General Information

PubChem CID

11984408

IUPAC Name

13-hydroxy-10,16-bis(2,4,6-trimethylphenyl)-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide

InChI Key

BEHLZZISBCRGSO-UHFFFAOYSA-N

SMILES

CC1=CC(=C(C(=C1)C)C2=CC3=CC=CC=C3C4=C2OP(=O)(OC5=C4C6=CC=CC=C6C=C5C7=C(C=C(C=C7C)C)C)O)C

Application

Technical Notes:
1. Mannich Reaction: Catalyst for the enantioselectively highly-regioselective addition of a silyl dienolate to
imines in good yields to give a,ß-unsaturated õ amino carboxylic esters in one step.
2.Three-component reactions of aldehydes, anilines, and a-isocyanoacetamides in the presence of a catalytic amount of chiral phosphoric acid afforded the 5-(1 -aminoalkyl)-5-a minooxazole
References:
1.Angew. Chem. Int. Ed., 2008, 47, 3631-3634 .
2.Angew. Chem. Int. Ed., 2009, 48, 6717-6721.

References Data Source From Pubchem

Asymmetric Brønsted Acid Catalyzed Cycloadditions of ortho-Quinone Methides and Related Compounds

Publication Name: Synthesis

Publication Date: 2022-04-21

DOI: 10.1055/a-1781-6538

Recent Applications of the Diels–Alder Reaction in the Synthesis of Natural Products (2017–2020)

Publication Name: Synthesis

Publication Date: 2021-08-04

DOI: 10.1055/a-1532-4763

Enantioselective Minisci-Reaction of N-Heterocycles and Amides through Hydrogen-Atom Transfer

Publication Name: Synfacts

Publication Date: 2021-05-18

DOI: 10.1055/s-0040-1706201

Brønsted Acid Catalyzed Vinylogous Mannich Reaction