(S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98% (>99% ee) [(S)-AntPhos]|15-1967|1807740-34-6

(S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzo[d][1,3]oxaphosphole,98% (>99% ee) [(S)-AntPhos]

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Sku SC15-1967_500_MG
US-Strem
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Product Information

Product Name
(S)-4-(Anthracen-9-yl)-3-(t-butyl-2,3-dihydrobenzod1,3oxaphosphole,98% (>99% ee) (S)-AntPhos
Brand Name
US-Strem
Product Number
15-1967
CAS
1807740-34-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
101904696
IUPAC Name
(3S)-4-anthracen-9-yl-3-tert-butyl-2H-1,3-benzoxaphosphole
InChI Key
HKAWVLHXUZNLPP-HHHXNRCGSA-N
SMILES
CC(C)(C)P@@1COC2=CC=CC(=C21)C3=C4C=CC=CC4=CC5=CC=CC=C53

Safety Information

Storage Condition
Store at 2-8℃

Application

Technical Notes:
1. Ligand/palladium catalyst for general Miyaura borylation reactions .
2. Ligand/palladium catalyst for general and sterically demanding Suzuki-Miyaura cross-couplingreactions.
3. L igand/palladium catalyst for aryl-alkyl Suzuki-Miyaura cross-coupling reactions.
4. Ligand/nickel catalyst for intramolecular reductive cyclization.
5. Ligand/palladium catalyst for Dearomative cyclization.
References:
1. Org. Lett., 2011, 13,1366.
2. Chem. Eur. J., 2013. 19.2261.
3. Org. Chem. Front., 2014,1, 225.
4. Angew. Chem. Int. Ed., 2015, 54.2520. 5. Angew. Chem. Int. Ed., 2015, 54, 3033. 6. Tetrahedron, 2016, 72, 1 782.

References Data Source From Pubchem

Enantioselective Arylation of Oxindoles Using Modified BI-DIME Ligands
Publication Name: Synthesis
Publication Date: 2018-06-28
DOI: 10.1055/s-0036-1591590

Nickel-Catalyzed Enantioselective Reductive Cyclizations of Alkynones
Publication Name: Synfacts
Publication Date: 2015-03-18
DOI: 10.1055/s-0034-1380392