(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine, min. 97% (S,R)-N-PINAP|15-1787|1173836-08-2

(R)-(+)-4-[2-(Diphenylphosphino)-1-naphthalenyl]-N-[(S)-1-phenylethyl]-1-phthalazinamine, min. 97% (S,R)-N-PINAP

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Sku SC15-1787_250_MG
US-Strem
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Product Information

Product Name
(R)-(+)-4-2-(Diphenylphosphino)-1-naphthalenyl-N-(S)-1-phenylethyl-1-phthalazinamine, min. 97% (S,R)-N-PINAP
Brand Name
US-Strem
Product Number
15-1787
CAS
1173836-08-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
58174047
IUPAC Name
4-(2-diphenylphosphanylnaphthalen-1-yl)-N-(1S)-1-phenylethylphthalazin-1-amine
InChI Key
HCEVCINOBTVHOF-MHZLTWQESA-N
SMILES
CC@@H(C1=CC=CC=C1)NC2=NN=C(C3=CC=CC=C32)C4=C(C=CC5=CC=CC=C54)P(C6=CC=CC=C6)C7=CC=CC=C7

Application

Technical Notes：
1. The PINAP family of P,N ligands is a synthetically more accessible but a similarly performing analog of the QUINAP (15-1777, 15-1778) ligand in enantioselective hydroboration, alkyne addition, and azomethine cycloaddition reactions. (Ref. 1)
2.With copper, enantioselective addition of alkynes to aldehydes to synthesize propargylamines .
3.With copper, catalytic, enantioselective, conjugate alkyne addition in aqueous media.
References:
1.Angew. Chem. Int. Ed.. 2004, 43, 5971. 2.Org. Lott 2006.8, 2437.
3.J. Am. Chom. Soc.2005, 127. 9682.