(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP|15-1775|145964-33-6

(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP

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Sku SC15-1775_500_MG
US-Strem
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Product Information

Product Name
(R)-(+)-2-(Diphenylphosphino)-2'-methoxy-1,1'-binaphthyl, 99% (R)-MOP
Brand Name
US-Strem
Product Number
15-1775
CAS
145964-33-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
4190002
IUPAC Name
1-(2-methoxynaphthalen-1-yl)naphthalen-2-yl-diphenylphosphane
InChI Key
KRWTWSSMURUMDE-UHFFFAOYSA-N
SMILES
COC1=C(C2=CC=CC=C2C=C1)C3=C(C=CC4=CC=CC=C43)P(C5=CC=CC=C5)C6=CC=CC=C6

Application

Technical Notes:
1. Efficient catalyst for the e nantioselective hydrosilyation of 1 -alkenes to optically active 2-alcohols.
2.Ligand for palladium-catalyzed asymmetric reduction of allylic esters ,
3: L igand for the rhodium catalyzed asymmetric arylation of imines with organostannanes .
4. L igand for the rhodium-catalyzed asymmetric addition of aryl- and alkenylboronic acids to Isatins.
5. Ligand for desymmetrization of malonamides via an enantioselective intramolecular Buchwald-Hartwig reaction.
References:
1. J. Am. Chem. Soc.. 1991, 1 13, 9887.
2.Acc. Chem. Res., 2000, 33, 354. (review) . 3.J. Am. Chem. Soc., 1994, 116, 775.
4. J. Am. Chem. Soc., 2000, 122, 976. 5.Angew. Chem. Int. Ed.. 2006, 45, 3353. 6. Tetrahedron L ett., 2009, 50, 41 70

References Data Source From Pubchem

Structural Features of Cationic Palladium(II) Acetylacetonate Complexes with Dialkylbiarylphosphine Ligands
Publication Name: Journal of Structural Chemistry
Publication Date: 2025-05
DOI: 10.1134/s0022476625050191

Catalytic enantioselective synthesis of boron-stereogenic BODIPYs
Publication Name: Nature Synthesis
Publication Date: 2023-03-16
DOI: 10.1038/s44160-023-00262-1

Recent Advances of Group 10 Transition Metal Hydrosilylation Catalysts
Publication Name: Perspectives of Hydrosilylation Reactions
Publication Date: 2023
DOI: 10.1007/3418_2023_99

Hydrosilylation of Carbon–Carbon Multiple Bonds in Organic Synthesis
Publication Name: Perspectives of Hydrosilylation Reactions
Publication Date: 2023
DOI: 10.1007/3418_2023_105

Catalytic Enantioselective Synthesis of C–N Atropisomeric Heterobiaryls
Publication Name: Synthesis
Publication Date: 2022-02-23
DOI: 10.1055/s-0040-1719896