(S)-2,2'-Bis[bis(4-methoxy-3,5-di-t-butylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl, min. 97% (S)-DTBM-Garphos|15-1673|1365531-99-2

(S)-2,2'-Bis[bis(4-methoxy-3,5-di-t-butylphenyl)phosphino]-4,4',6,6'-tetramethoxy)-1,1'-biphenyl, min. 97% (S)-DTBM-Garphos

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Product Information

Product Name
(S)-2,2'-Bisbis(4-methoxy-3,5-di-t-butylphenyl)phosphino-4,4',6,6'-tetramethoxy)-1,1'-biphenyl, min. 97% (S)-DTBM-Garphos
Brand Name
US-Strem
Product Number
15-1673
CAS
1365531-99-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
87110675
IUPAC Name
2-2-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphanyl-4,6-dimethoxyphenyl-3,5-dimethoxyphenyl-bis(3,5-ditert-butyl-4-methoxyphenyl)phosphane
InChI Key
KACYLFSRRUJDSY-UHFFFAOYSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1OC)C(C)(C)C)P(C2=CC(=C(C(=C2)C(C)(C)C)OC)C(C)(C)C)C3=CC(=CC(=C3C4=C(C=C(C=C4P(C5=CC(=C(C(=C5)C(C)(C)C)OC)C(C)(C)C)C6=CC(=C(C(=C6)C(C)(C)C)OC)C(C)(C)C)OC)OC)OC)OC

Application

Technical Note:
1. Chiral ligand used in the preparation of hydrogenation catalysts with exceptionally high activity and selectivity.
Reference:
1. US Patent Application No. 61/381 ,493.

References Data Source From Pubchem

Radical Intermediates as Coupling Partners
Publication Name: Science of Synthesis
Publication Date: 2023