(R)-(+)-7-[N-(2-Phenylthio)ethylamino]-7'-[diphenylphosphino]-2,2',3,3'-tetrahydro-1,1'-spirobindane, 97+% (>99% ee) [(R)-Ph-SpiroSAP-Ph]|15-1643|1809609-40-2

(R)-(+)-7-[N-(2-Phenylthio)ethylamino]-7'-[diphenylphosphino]-2,2',3,3'-tetrahydro-1,1'-spirobindane, 97+% (>99% ee) [(R)-Ph-SpiroSAP-Ph]

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Sku SC15-1643_100_MG
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Product Information

Product Name
(R)-(+)-7-N-(2-Phenylthio)ethylamino-7'-diphenylphosphino-2,2',3,3'-tetrahydro-1,1'-spirobindane, 97+% (>99% ee) (R)-Ph-SpiroSAP-Ph
Brand Name
US-Strem
Product Number
15-1643
CAS
1809609-40-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
124220162
IUPAC Name
(3R)-4'-diphenylphosphanyl-N-(2-phenylsulfanylethyl)-3,3'-spirobi1,2-dihydroindene-4-amine
InChI Key
TULSCBZXLKGSEX-DIPNUNPCSA-N
SMILES
C1CC@@2(CCC3=C2C(=CC=C3)P(C4=CC=CC=C4)C5=CC=CC=C5)C6=C1C=CC=C6NCCSC7=CC=CC=C7

Application

Technical Notes:
1. Catalyst used for the asymmetric hydrogenation of ß-alkyl- ß-ketoesters .
Reference:
1. Angew. Chem. Int. Ed., 2015, 54, 8791.