(R)-(+)-7-[N-(2-Benzylthio)ethylamino]-7'-[bis(3,5-di-t-butylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobindane, 97+% (>99% ee) [(R)-DTB-SpiroSAP-Bn]|15-1613|1809609-52-6

(R)-(+)-7-[N-(2-Benzylthio)ethylamino]-7'-[bis(3,5-di-t-butylphenyl)phosphino]-2,2',3,3'-tetrahydro-1,1'-spirobindane, 97+% (>99% ee) [(R)-DTB-SpiroSAP-Bn]

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Product Information

Product Name
(R)-(+)-7-N-(2-Benzylthio)ethylamino-7'-bis(3,5-di-t-butylphenyl)phosphino-2,2',3,3'-tetrahydro-1,1'-spirobindane, 97+% (>99% ee) (R)-DTB-SpiroSAP-Bn
Brand Name
US-Strem
Product Number
15-1613
CAS
1809609-52-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
124220159
IUPAC Name
(3R)-N-(2-benzylsulfanylethyl)-4'-bis(3,5-ditert-butylphenyl)phosphanyl-3,3'-spirobi1,2-dihydroindene-4-amine
InChI Key
KCPKRTWDDWPCHY-AXAMJWTMSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1)P(C2=CC=CC3=C2C@4(CCC5=C4C(=CC=C5)NCCSCC6=CC=CC=C6)CC3)C7=CC(=CC(=C7)C(C)(C)C)C(C)(C)C)C(C)(C)C

Application

Technical Notes:
1. Catalyst used for the as ymmetric hydrogenation of ß-alkyI- ß-ketoesters.
Reference:
1. Angew. Chem. Int. Ed., 2015, 54, 8791.