(3aR,8aR)-(-)-4,4,8,8-Tetrakis(3,5-diethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin|15-1517|1187446-93-0

(3aR,8aR)-(-)-4,4,8,8-Tetrakis(3,5-diethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

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Product Information

Product Name
(3aR,8aR)-(-)-4,4,8,8-Tetrakis(3,5-diethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo4,5-edioxaphosphepin
Brand Name
US-Strem
Product Number
15-1517
CAS
1187446-93-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
44474534
IUPAC Name
(3aR,8aR)-4,4,8,8-tetrakis(3,5-diethylphenyl)-2,2-dimethyl-6-phenyl-3a,8a-dihydro-1,3dioxolo4,5-e1,3,2dioxaphosphepine
InChI Key
BNAMLZQDVVNLSE-CDKYPKJRSA-N
SMILES
CCC1=CC(=CC(=C1)C2(C@H3C@H(C(OP(O2)C4=CC=CC=C4)(C5=CC(=CC(=C5)CC)CC)C6=CC(=CC(=C6)CC)CC)OC(O3)(C)C)C7=CC(=CC(=C7)CC)CC)CC

Application

Technical Note:
1. Chiral ligand used in the platinum-catalyzed, enantioselective diboration of terminal alkenes.
Reference:
1. J. Am. Chem. Soc. 2009, 131. 13210.

References Data Source From Pubchem

Enantioselective Diboration of Terminal Alkenes
Publication Name: Science of Synthesis
Publication Date: 2012