(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-di-i-propylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin|15-1514|1422371-27-4

(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-di-i-propylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

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Product Information

Product Name
(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-di-i-propylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo4,5-edioxaphosphepin
Brand Name
US-Strem
Product Number
15-1514
CAS
1422371-27-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
71583786
IUPAC Name
(3aS,8aS)-4,4,8,8-tetrakis3,5-di(propan-2-yl)phenyl-2,2-dimethyl-6-phenyl-3a,8a-dihydro-1,3dioxolo4,5-e1,3,2dioxaphosphepine
InChI Key
AYBKPJJNIOLFCE-YQOHNZFASA-N
SMILES
CC(C)C1=CC(=CC(=C1)C2(C@@H3C@@H(C(OP(O2)C4=CC=CC=C4)(C5=CC(=CC(=C5)C(C)C)C(C)C)C6=CC(=CC(=C6)C(C)C)C(C)C)OC(O3)(C)C)C7=CC(=CC(=C7)C(C)C)C(C)C)C(C)C

Application

Technical Note:
1. Chiral ligand for the platinum-catalyzed enantioselective diboration of monosubstituted alkenes.
2.Regio- and stereoselective homologation of 1 ,2-bis(boronic esters): stereocontrolled synthesis of 1,3-diol
References:
1. J. Am. Chem. Soc._ 2013, 135, 11222. 2.Angew. Chem.Int. Ed., 2016, 55, 14663.

References Data Source From Pubchem

Applications in the Synthesis of Medicinal and Natural Compounds
Publication Name: Science of Synthesis
Publication Date: 2019