(3aR,8aR)-(-)-4,4,8,8-Tetrakis(3,5-di-i-propylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin|15-1513|1361146-90-8

(3aR,8aR)-(-)-4,4,8,8-Tetrakis(3,5-di-i-propylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

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Product Information

Product Name
(3aR,8aR)-(-)-4,4,8,8-Tetrakis(3,5-di-i-propylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo4,5-edioxaphosphepin
Brand Name
US-Strem
Product Number
15-1513
CAS
1361146-90-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
57327639
IUPAC Name
(3aR,8aR)-4,4,8,8-tetrakis3,5-di(propan-2-yl)phenyl-2,2-dimethyl-6-phenyl-3a,8a-dihydro-1,3dioxolo4,5-e1,3,2dioxaphosphepine
InChI Key
AYBKPJJNIOLFCE-YZCGSYMESA-N
SMILES
CC(C)C1=CC(=CC(=C1)C2(C@H3C@H(C(OP(O2)C4=CC=CC=C4)(C5=CC(=CC(=C5)C(C)C)C(C)C)C6=CC(=CC(=C6)C(C)C)C(C)C)OC(O3)(C)C)C7=CC(=CC(=C7)C(C)C)C(C)C)C(C)C

Application

Technical Notes:
1. Chiral ligand used in a platinum catalyzed, enantios elective terpene construction.
2. Chiral ligand used in a platinum-catalyzed, diboration of aliphatic 1-alkenes .
3.. Regio- and stereos elective homologation of 1 ,2-bis(boronic esters): s tereocontrolled s ynthesis of 1 ,3-diols. 4. Synthesis of ß-lactams by palladium( 0)-catalyzed C(sp )-H carbamoylation.
References:
1.J. Am. Chem. Soc., 2013, 135, 2501.
2.J. Am. Chem. Soc., 2013, 135, 11222.
4.Angew. Chem. Int. Ed., 2016, 55, 14663. 4.Angew. c hem. Int. Ed., 2017, 56, 7218.

References Data Source From Pubchem

Synthesis by Borylation of Vinylboronates
Publication Name: Science of Synthesis
Publication Date: 2023