(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin|15-1512|1169835-86-2

(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo[4,5-e]dioxaphosphepin

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Product Information

Product Name
(3aS,8aS)-(+)-4,4,8,8-Tetrakis(3,5-dimethylphenyl)tetrahydro-2,2-dimethyl-6-phenyl-1,3-dioxolo4,5-edioxaphosphepin
Brand Name
US-Strem
Product Number
15-1512
CAS
1169835-86-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
121237548
IUPAC Name
(3aS,8aS)-4,4,8,8-tetrakis(3,5-dimethylphenyl)-2,2-dimethyl-6-phenyl-3a,8a-dihydro-1,3dioxolo4,5-e1,3,2dioxaphosphepine
InChI Key
DDFDBVZPMGPWLR-COCZKOEFSA-N
SMILES
CC1=CC(=CC(=C1)C2(C@@H3C@@H(C(OP(O2)C4=CC=CC=C4)(C5=CC(=CC(=C5)C)C)C6=CC(=CC(=C6)C)C)OC(O3)(C)C)C7=CC(=CC(=C7)C)C)C

Application

Technical Notes:
1.Chiral ligand used in the nickel-catalyzed, enantios elective, conjugate allylation of activated enones.
2.Chiral ligand used in the platinum-catalyzed, asymmetric, 1 ,4-dihydroxylation of 1,3-dienes via catalytic enantios electivediboration.
3.Chiral ligand used in the platinum-catalyzed, asymmetric addition of Bz(pin)z to N-silyl imines for the synthesis of a- aminoboronates.
4. Asymmetric 1,4 dihydroxylation of 1,3 dienes by catalytic enantios elective diboration.
References:
1. J. Am. Chem. Soc., 2008, 130, 4978.
2.J. Am. Chem. Soc.,2009, 131, 9134.
3.J. Am. Chem. Soc., 2013, 135, 9252 .
4.Chem. Sci., 2015, 6, 51 64.