(11bR)-4-Hydroxy-2,6-bis[4-(trifluoromethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (99% ee)|15-1392|791616-59-6

(11bR)-4-Hydroxy-2,6-bis[4-(trifluoromethyl)phenyl]-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 95%, (99% ee)

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Product Information

Product Name
(11bR)-4-Hydroxy-2,6-bis4-(trifluoromethyl)phenyl-4-oxide-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 95%, (99% ee)
Brand Name
US-Strem
Product Number
15-1392
CAS
791616-59-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
23110757
IUPAC Name
13-hydroxy-10,16-bis4-(trifluoromethyl)phenyl-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
InChI Key
WTTAZMHSXLJOIR-UHFFFAOYSA-N
SMILES
C1=CC=C2C(=C1)C=C(C3=C2C4=C(C(=CC5=CC=CC=C54)C6=CC=C(C=C6)C(F)(F)F)OP(=O)(O3)O)C7=CC=C(C=C7)C(F)(F)F

Application

Technical Note:
1.Hydrophosphonylation: Catalyst for the highly enantioselective hydrophosphonylation reaction of diisopropyl phosphite with aldimine to give a-amino.
Reference:
1. Tetrahedron L ett., 2009, 65, 4950-4956.

References Data Source From Pubchem

Enantioselective Mannich-Type Reaction with Rhodium(II)
Publication Name: Science of Synthesis
Publication Date: 2019

Enantioselective Carbonyl Ylide Reduction with Rhodium(II)
Publication Name: Science of Synthesis
Publication Date: 2019

Highly enantioselective trapping of zwitterionic intermediates by imines.
Publication Name: Nature Chemistry
Publication Date: 2012-07-29
DOI: 10.1038/nchem.1406