(11bS)-4-Hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)|15-1391|874948-60-4

(11bS)-4-Hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)

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Product Information

Product Name
(11bS)-4-Hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 98%, (99% ee)
Brand Name
US-Strem
Product Number
15-1391
CAS
874948-60-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
15948415
IUPAC Name
13-hydroxy-10,16-dinaphthalen-2-yl-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
InChI Key
IHLZSTKPUGDSET-UHFFFAOYSA-N
SMILES
C1=CC=C2C=C(C=CC2=C1)C3=CC4=CC=CC=C4C5=C3OP(=O)(OC6=C5C7=CC=CC=C7C=C6C8=CC9=CC=CC=C9C=C8)O

Application

Technical Note:
1.Nucleophilic Substitution: Catalyst for the nucleophilic substitution involving 3-hydroxyoxindoles giving 3,3'-disubstituted oxindoles with concomitant generation of an all-carbon quaternary stereogenic center in high yield and excellent enantioselectivity.
Reference:
1.Angew. Chem. Int. Ed., 2012, 51, 1046-1050.

References Data Source From Pubchem

Discovery of GPR84 Fluorogenic Probes Based on a Novel Antagonist for GPR84 Bioimaging
Publication Name: Journal of Medicinal Chemistry
Publication Date: 2024-07-01
DOI: 10.1021/acs.jmedchem.4c00359

Highly enantioselective trapping of zwitterionic intermediates by imines.
Publication Name: Nature Chemistry
Publication Date: 2012-07-29
DOI: 10.1038/nchem.1406

Organocatalytic Synthesis of Spiro[pyrrolidin-3,3′-oxindoles]
Publication Name: Synfacts
Publication Date: 2009-10-22
DOI: 10.1055/s-0029-1218115