(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)|15-1378|922711-75-9

(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)

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Product Information

Product Name
(11bR)-8,9,10,11,12,13,14,15-Octahydro-4-hydroxy-2,6-di-2-naphthalenyl-4-oxide-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 98%, (99% ee)
Brand Name
US-Strem
Product Number
15-1378
CAS
922711-75-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
25185356
IUPAC Name
13-hydroxy-10,16-dinaphthalen-2-yl-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(23),2,8,10,15,17-hexaene 13-oxide
InChI Key
UQNXHNASBPBCCD-UHFFFAOYSA-N
SMILES
C1CCC2=C3C4=C5CCCCC5=CC(=C4OP(=O)(OC3=C(C=C2C1)C6=CC7=CC=CC=C7C=C6)O)C8=CC9=CC=CC=C9C=C8

Application

Technical Notes:
1.The preparation of binaphthol monophosphoric acid derivatives.
2.Organocatalyst developed for the diastereo- and enantioselective 1 4-conjugate addn. of a variety of
ß-ketoesters to nitroolefins, employed in the addn. re action, providing the corre sponding nitroalkanes in high yield (up to 97%) with moderate diastereoselectivities (up to 2.6:1 dr) and enantioselectivities (up to 58% ee).
References: 1.JP 4725757, EP 1038877, US 6274745, 2000-3-21. 2. Lett. in Org. Chem., 2010, 7, 219-225.

References Data Source From Pubchem

Catalytic Asymmetric Substitution Reaction of 3-Substituted 2-Indolylmethanols with 2-Naphthols
Publication Name: Synthesis
Publication Date: 2020-08-17
DOI: 10.1055/s-0040-1707237