(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)|15-1367|878111-17-2

(11bS)-2,6-Bis[3,5-bis(trifluoromethyl)phenyl]-4-hydroxy-4-oxide-dinaphtho[2,1-d:1',2'-f][1,3,2]dioxaphosphepin, 98%, (99% ee)

$198.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-1367_100_MG
US-Strem
Get Bulk Quote

Product Information

Product Name
(11bS)-2,6-Bis3,5-bis(trifluoromethyl)phenyl-4-hydroxy-4-oxide-dinaphtho2,1-d:1',2'-f1,3,2dioxaphosphepin, 98%, (99% ee)
Brand Name
US-Strem
Product Number
15-1367
CAS
878111-17-2
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11468389
IUPAC Name
10,16-bis3,5-bis(trifluoromethyl)phenyl-13-hydroxy-12,14-dioxa-13λ5-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene 13-oxide
InChI Key
DQORDVSQWPKAQJ-UHFFFAOYSA-N
SMILES
C1=CC=C2C(=C1)C=C(C3=C2C4=C(C(=CC5=CC=CC=C54)C6=CC(=CC(=C6)C(F)(F)F)C(F)(F)F)OP(=O)(O3)O)C7=CC(=CC(=C7)C(F)(F)F)C(F)(F)F

Application

Technical Note:
1.Friedel-Crafts Alkylation: Chiral phosphoric acids were used as catalysts for the Friedel-Crafts alkylations of indolyl enones while both a ruthenium complex and chiral phosphoric acids were used as catalysts for sequential olefin cross-metathesis and Friedel-Crafts alkylations of allyloxymethyl or allylaminomethyl indoles and enones.
Reference:
1. Angew. Chem. Int. Ed., 2009, 48, 7428-7431.

References Data Source From Pubchem

Enantioselective Addition of Oxonium Ylides to ortho-Quinomethanes with Rhodium(II)
Publication Name: Science of Synthesis
Publication Date: 2019

Chiral Pyrophosphoric Acid Catalysts for the para-Selective and Enantioselective Aza-Friedel–Crafts Reaction of Phenols
Publication Name: Synthesis
Publication Date: 2018-08-22
DOI: 10.1055/s-0037-1610250

Asymmetric Cycloetherification by Bifunctional Organocatalyst
Publication Name: Synthesis
Publication Date: 2018-06-26
DOI: 10.1055/s-0036-1591592

Spirocyclic Orthoesters, Orthothioesters and Orthoaminals in the Synthesis and Structural Modification of Natural Products
Publication Name: Synthesis
Publication Date: 2016-12-30
DOI: 10.1055/s-0036-1588339

Enantioselective amine alpha-functionalization via palladium-catalysed C-H arylation of thioamides.
Publication Name: Nature Chemistry
Publication Date: 2016-10-03
DOI: 10.1038/nchem.2619