Product Name
N-2-(di-1-adamantylphosphino)phenylmorpholine, 98% Mor-DalPhos
Certificate of Analysis (COA)
IUPAC Name
bis(1-adamantyl)-(2-morpholin-4-ylphenyl)phosphane
InChI Key
CCBRRSUORFMQCZ-UHFFFAOYSA-N
SMILES
C1COCCN1C2=CC=CC=C2P(C34CC5CC(C3)CC(C5)C4)C67CC8CC(C6)CC(C8)C7
Technical Notes:
1. PN-ligandfor use inthe Pd-catalyzed cross-coupling of ammonia and hydrazine:Ref. (2) with adiverse rangeof sercalybinerea, anblaseaarye hor deswiiowcatalystloading andmiaconaitions.ket) withdlamines ina
2.P-N-ligand for the gold-catalyzed stereoselective hydroamination of internal alkynes with dialkylamines to afford E-amines.
3.P-N-ligand for use in the Pd-catalyzed for mono -cx arylation of ketones employing aryl chlorides, bromides, iodides, mesylates(Ref.7)andtosvlates
References:
1.Angew. Chem. Int. Ed., 2010, 49, 4071 .
2.Angew. Chem. Int. Ed., 2010, 49, 8686.
3.J. Am. Chem. Soc., 2010, 132, 18026.
4.J. Am. Chem. Soc., 2011 , 133, 51 94.
5.J. Org. Chem., 2012, 77, 1056.
6.Eur. J. Org. Chem., 2012, 3972.
7. Angew. Chem. Int. Ed., 2013, 52, 7242.
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