2-(Di-1-adamantylphosphino)dimethylaminobenzene, 97% Me-DalPhos|15-1090|1219080-77-9

2-(Di-1-adamantylphosphino)dimethylaminobenzene, 97% Me-DalPhos

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Sku SC15-1090_250_MG
US-Strem
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Product Information

Product Name
2-(Di-1-adamantylphosphino)dimethylaminobenzene, 97% Me-DalPhos
Brand Name
US-Strem
Product Number
15-1090
CAS
1219080-77-9
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
45278337
IUPAC Name
2-bis(1-adamantyl)phosphanyl-N,N-dimethylaniline
InChI Key
MILNYLCUWRWYBI-UHFFFAOYSA-N
SMILES
CN(C)C1=CC=CC=C1P(C23CC4CC(C2)CC(C4)C3)C56CC7CC(C5)CC(C7)C6

Application

Technical Note:
1. Versatile ligand for the palladium- catalyzed amination of aryl and heteroaryl chlorides with primary aryl and alkylamines, cyclic and acyclic amines, lithium amide, N-H imines, hydrazones and ammonia.
Reference:
1. Chem. Eur.J., 2010, 16, 1983.

References Data Source From Pubchem

Catalytic reactions with low-valency ambiphilic gallium complexes
Publication Name: Nature Synthesis
Publication Date: 2024-05-15
DOI: 10.1038/s44160-024-00557-x

Gold carbene complexes and beyond: new avenues in gold(I)-carbon coordination chemistry
Publication Name: Gold Bulletin
Publication Date: 2022-01-03
DOI: 10.1007/s13404-021-00298-1

A Highly Versatile Catalyst System for the Cross‐Coupling of Aryl Chlorides and Amines
Publication Name: Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Date: 2010-01-28
DOI: 10.1002/chem.200902316