(3R,3'R,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin, 95% (S)-BINAPINE|15-1053|528854-26-4

(3R,3'R,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho[2,1-c:1',2'-e]phosphepin, 95% (S)-BINAPINE

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Product Information

Product Name
(3R,3'R,4S,4'S,11bS,11'bS)-(+)-4,4'-Di-t-butyl-4,4',5,5'-tetrahydro-3,3'-bi-3H-dinaphtho2,1-c:1',2'-ephosphepin, 95% (S)-BINAPINE
Brand Name
US-Strem
Product Number
15-1053
CAS
528854-26-4
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
66557332
IUPAC Name
(12S)-13-tert-butyl-12-(12S)-13-tert-butyl-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaen-12-yl-13-phosphapentacyclo13.8.0.02,11.03,8.018,23tricosa-1(15),2(11),3,5,7,9,16,18,20,22-decaene
InChI Key
YXMFQIWDFKIXGQ-KUSQLHRJSA-N
SMILES
CC(C)(C)P1CC2=C(C3=CC=CC=C3C=C2)C4=C(C@H1C@@H5C6=C(C7=CC=CC=C7C=C6)C8=C(CP5C(C)(C)C)C=CC9=CC=CC=C98)C=CC1=CC=CC=C14

Application

Technical Notes:
1. Palladium-catalyzed a-arylation of tetramic acids.
2. Palladium-catalyzed domino process to spirooxindoles: L igand effect on aminopalladation versus carbopalladation.
3. An integrated microsystem for self-optimization of a Heck reaction: F rom micro- to mesoscale flow systems.
4.Synthesis of 5-alkyl-5-aryl-1-pyrroline N-oxides from 1-aryl-substituted nitroalkanes and acrolein via Michael addition and nitro reductive cyclization.