(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand|15-0964|205495-66-5

(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand

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Product Information

Product Name
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (S,S)-DACH-Naphthyl Trost Ligand
Brand Name
US-Strem
Product Number
15-0964
CAS
205495-66-5
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
11767928
IUPAC Name
2-diphenylphosphanyl-N-(1S,2S)-2-(2-diphenylphosphanylnaphthalene-1-carbonyl)aminocyclohexylnaphthalene-1-carboxamide
InChI Key
VXFKMKXTPXVEMU-ZYBCLOSLSA-N
SMILES
C1CCC@@H(C@H(C1)NC(=O)C2=C(C=CC3=CC=CC=C32)P(C4=CC=CC=C4)C5=CC=CC=C5)NC(=O)C6=C(C=CC7=CC=CC=C76)P(C8=CC=CC=C8)C9=CC=CC=C9

Application

Technical Note:
1.The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon, nitrogen，oxygen，and seleno nucleopiles
References:
1.Angew. Chem., Int. Ed., 2002, 41, 3492.
2.Angew. Chem., Int. Ed., 1996, 35, 99.
3.Tetrahedron L ett., 1998, 39, 1 713.
4.Org. L ett. 2011, 13, 3336.
5.Org. L ett. 2007, 9, 3961.

References Data Source From Pubchem

Asymmetric Total Synthesis of (2R)-Hydroxynorneomajucin
Publication Name: Synfacts
Publication Date: 2022-06-15
DOI: 10.1055/s-0041-1738544

Recent Advances in the Construction of Quaternary Stereocenters via Palladium-Catalyzed Decarboxylative Asymmetric Allylic Alkylation
Publication Name: Synthesis
Publication Date: 2021-07-22
DOI: 10.1055/a-1533-3085

Asymmetric Synthesis of Ethers by Catalytic Alkene Hydro­alkoxy­lation
Publication Name: Synthesis
Publication Date: 2020-04-14
DOI: 10.1055/s-0039-1690874

Deployment of Aziridines for the Synthesis of Alkaloids and Their Derivatives
Publication Name: Synthesis
Publication Date: 2019-02-18
DOI: 10.1055/s-0037-1611715

Palladium-Catalyzed Asymmetric Allylic Alkylation Strategies for the Synthesis of Acyclic Tetrasubstituted Stereocenters
Publication Name: Synthesis
Publication Date: 2018-12-05
DOI: 10.1055/s-0037-1610386