Product Name
(1R,2R)-(+)-1,2-Diaminocyclohexane-N,N'-bis(2-diphenylphosphino-1-naphthoyl), min. 94% (R,R)-DACH-Naphthyl Trost Ligand
Certificate of Analysis (COA)
IUPAC Name
2-diphenylphosphanyl-N-(1R,2R)-2-(2-diphenylphosphanylnaphthalene-1-carbonyl)aminocyclohexylnaphthalene-1-carboxamide
InChI Key
VXFKMKXTPXVEMU-AWSIMMLFSA-N
SMILES
C1CCC@H(C@@H(C1)NC(=O)C2=C(C=CC3=CC=CC=C32)P(C4=CC=CC=C4)C5=CC=CC=C5)NC(=O)C6=C(C=CC7=CC=CC=C76)P(C8=CC=CC=C8)C9=CC=CC=C9
Technical Note:
1. The palladium complexes of the Trost ligands are effective in a variety of allylic substitution reactions involving carbon,nitrogen, oxygen. and fluorides nucleophiles.
References:
1.J. Am. Chem. Soc., 2011, 133, 7328.
2.Angew. Chem., Int. Ed., 1996, 35, 99.
3.Tetrahedron L ett., 1998, 39, 1 713.
4.J. Am. Chem. Soc., 2001, 123, 4366.
5.J. Am. Chem. Soc., 2008, 130, 1 1852.
6.J. Am. C hem. Soc., 2003, 125, 6066.
7.J. Am. Chem. Soc., 2011, 133, 1 5902.
![(R)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide], 98% (99% ee)|15-0312|94041-16-4](http://www.jk-sci.com/cdn/shop/files/3117e307f3d0924dbdc43a92206364d2_200x200_crop_center.jpg?v=1784770208)
