(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand

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Sku SC15-0961_100_MG
US-Strem
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General Details
CAS # 169689-05-8
SMILES
Chemical Purity
Molecular Formula C44H40N2O2P2
Chemical Formula
Formula Weight 690.76
Reaction
Note
Physical Properties
Purity 95%
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Note: 1.The palladium complexes of the Trost ligands are effective in a variety of allylic subs titution reactions involving carbon,nitrogen, oxygen, sulfur, and fluorides nucleophiles.
References:
1.Angew. Chem., Int. Ed. 1997, 36, 2635.

2 .J. Am. Chem. Soc. 1995, 1 17, 7247.
3.J. Am. Chem. Soc. 2011, 133, 2061 1.
4.Angew. C hem.,Int. Ed.1996, 35, 99.
5.Tetrahedron Lett., 1998, 39, 1 71 3.
6.Org. L ett., 2007, 9, 2357.
7.J. Am. Chem. Soc., 1998, 120, 815.
8.J. Am. Chem. Soc., 2003, 125, 6066.
9.Tetrahedron L ett., 2000, 4 1, 3809.
10.J. Am. Chem. Soc., 2010, 132, 1 7402.