Product Name
(1S,2S)-(-)-1,2-Diaminocyclohexane-N,N'-bis(2'-diphenylphosphinobenzoyl), 95% (S,S)-DACH-Phenyl Trost Ligand
Certificate of Analysis (COA)
IUPAC Name
2-diphenylphosphanyl-N-(1S,2S)-2-(2-diphenylphosphanylbenzoyl)aminocyclohexylbenzamide
InChI Key
AXMSEDAJMGFTLR-ZAQUEYBZSA-N
SMILES
C1CCC@@H(C@H(C1)NC(=O)C2=CC=CC=C2P(C3=CC=CC=C3)C4=CC=CC=C4)NC(=O)C5=CC=CC=C5P(C6=CC=CC=C6)C7=CC=CC=C7
Technical Note:
1.The palladium complexes of the Trost ligands are effective in a variety of allylic subs titution reactions involving carbon,nitrogen, oxygen, sulfur, and fluorides nucleophiles.
References:
1.Angew. Chem., Int. Ed. 1997, 36, 2635.
2 .J. Am. Chem. Soc. 1995, 1 17, 7247.
3.J. Am. Chem. Soc. 2011, 133, 2061 1.
4.Angew. C hem.,Int. Ed.1996, 35, 99.
5.Tetrahedron Lett., 1998, 39, 1 71 3.
6.Org. L ett., 2007, 9, 2357.
7.J. Am. Chem. Soc., 1998, 120, 815.
8.J. Am. Chem. Soc., 2003, 125, 6066.
9.Tetrahedron L ett., 2000, 4 1, 3809.
10.J. Am. Chem. Soc., 2010, 132, 1 7402.
Cycloadditions
Publication Name: Science of Synthesis
Publication Date: 2022
![(R)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide], 98% (99% ee)|15-0312|94041-16-4](http://www.jk-sci.com/cdn/shop/files/3117e307f3d0924dbdc43a92206364d2_200x200_crop_center.jpg?v=1784770208)
