(R,R)-(-)-1,2-Bis[(2-methoxyphenyl)(phenyl)phosphino]ethane, 98% (-)-DIPAMP|15-0481|55739-58-7

(R,R)-(-)-1,2-Bis[(2-methoxyphenyl)(phenyl)phosphino]ethane, 98% (-)-DIPAMP

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Sku SC15-0481_250_MG
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Product Information

Product Name
(R,R)-(-)-1,2-Bis(2-methoxyphenyl)(phenyl)phosphinoethane, 98% (-)-DIPAMP
Brand Name
US-Strem
Product Number
15-0481
CAS
55739-58-7
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10884975
IUPAC Name
(2-methoxyphenyl)-2-(2-methoxyphenyl)-phenylphosphanylethyl-phenylphosphane
InChI Key
QKZWXPLBVCKXNQ-ROJLCIKYSA-N
SMILES
COC1=CC=CC=C1P@(CCP@(C2=CC=CC=C2)C3=CC=CC=C3OC)C4=CC=CC=C4

Application

Technical Note:
1. Rhodium DIPAMP catalysts have shown high activity and enantios electivity in the asymmetric hydrogenation of enamides, enol
acetates and olefins.
References:
1. ACS Symposium Series, 1993, 517 (Selectivity in Catalysis), 58-74 (review). 2. Acc. Chem. Res.. 1983, 16, 106 (review).

References Data Source From Pubchem

Construction of Quaternary Allylic Amino Acid Derivatives through Palladium-Catalyzed Allylic Alkylation Reaction of Azlactones with Vinyl Aziridine
Publication Name: Synthesis
Publication Date: 2022-07-27
DOI: 10.1055/a-1878-8084

Investigations into the Formation and Stability of Cationic Rhodium Diphosphane η6‐Arene Complexes
Publication Name: Chemistry (Weinheim an der Bergstrasse, Germany)
Publication Date: 2012-08-22
DOI: 10.1002/chem.201201587

[3 + 2]Annulation Using Chiral 1,2-Bis[(2-methoxyphenyl)(phenyl)phosphino]ethane
Publication Name: Science of Synthesis
Publication Date: 2012

Profiling the tuneable R-SMS-Phos structure in the rhodium(i)-catalyzed hydrogenation of olefins: the last stand?
Publication Name: Organic & Biomolecular Chemistry
Publication Date: 2011-07-21
DOI: 10.1039/c1ob05364g

Trinuclear Rhodium Complexes and Their Relevance for Asymmetric Hydrogenation
Publication Name: Chemistry – An Asian Journal
Publication Date: 2008-10-28
DOI: 10.1002/asia.200800184