(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*|15-0126|866081-62-1

(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*

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Sku SC15-0126_100_MG
US-Strem
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Product Information

Product Name
(R,R)-(-)-2,3-Bis(t-butylmethylphosphino)quinoxaline, min. 98% (R,R)-QuinoxP*
Brand Name
US-Strem
Product Number
15-0126
CAS
866081-62-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
16218188
IUPAC Name
tert-butyl-3-tert-butyl(methyl)phosphanylquinoxalin-2-yl-methylphosphane
InChI Key
DRZBLHZZDMCPGX-UHFFFAOYSA-N
SMILES
CC(C)(C)P(C)C1=NC2=CC=CC=C2N=C1P(C)C(C)(C)C

Application

Technical Notes:
1.L igand for the rhodium-catalyzed, asymmetric hydrogenation of dehydroamino acid esters and a-enamides.
2.Ligand for the rhodium-catalyzed, asymmetric 1,4-addition of arylboronic acids to a,ß-unsaturated carbonyl compounds.
3.Ligand for the rhodium-catalyzed, asymmetric alkylative ring opening reaction
4.Ligand for the palladium catalyzed asymmetric allylic alkylation and amination of racemic substrates.
5.Ligand for the ruthenium-catalyzed asymmetric hydrogenation of ketones.
6.Ligand for the rhodium-catalyzed, asymmetric hydroacylation of 1,1-disubstituted alkenes with aldehydes .
7.Ligand for the silver-catalyzed asymmetric nitroso aldol reaction
8. Cu- catalyzed enantioconvergent allyllic borylation.
9.Cu-catalyzed enantioselective cyclopropylation.

References Data Source From Pubchem

Recent Advances in Transition-Metal-Catalyzed Asymmetric Functionalization of Enamides
Publication Name: Synthesis
Publication Date: 2022-08-18
DOI: 10.1055/a-1892-5473

Enantioselective Cobalt-Catalyzed C–H Functionalization
Publication Name: Synthesis
Publication Date: 2022-05-12
DOI: 10.1055/a-1801-2595

Rhodium-Catalyzed Enantioselective Ring Expansion of Azetidines
Publication Name: Synfacts
Publication Date: 2022-04-20
DOI: 10.1055/s-0041-1737440

Copper-Catalyzed Silylamination for the Synthesis of β-Silyl-α-amino Acids
Publication Name: Synfacts
Publication Date: 2022-04-20
DOI: 10.1055/s-0041-1737569

Transition-Metal-Catalyzed Enantioselective Synthesis of Indoles from 2-Alkynylanilines
Publication Name: Synthesis
Publication Date: 2022-02-22
DOI: 10.1055/a-1729-9572