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Sku SC15-0107_1_G
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General Details
CAS # 121627-17-6
SMILES
Chemical Purity
Molecular Formula C46H44O8P2·;0.5EtOAc
Chemical Formula
Formula Weight 786.78 (830.84)
Reaction
Note
Physical Properties
Purity min. 95%
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1.With rhodium forms a highly active catalyst for the hydroformylation of a olefins .
2.The hydroformylation of functionalized a-olefins is highly regios elective. The sterically demanding ligand increases n/iso ratio by reducing rhodium interaction with heteroatom functionality
3. Ligand used in tandem reaction sequences where high n/iso ratio is desired in the hydroformylation step
References:
1.US Patent 47 69498.
2.J. Am. Chem. Soc., 1993, 1 15, 2066.
3.Organometallics, 1995, 14, 3832.
4.J. Mol. Catal. A, 2005, 232, 41.
5.J. Org. Chem. 1995, 60, 7078.
6.J. Org. Chem. 2007, 72, 1871.
7.Chem. Rev.1999, 99, 3329.