6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS|15-0107|121627-17-6

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS

$351.00

FREE
SHIPPING

100% MONEY
BACK GUARANTEE

ONLINE
SUPPORT 24/7

Available on backorder. No lead time available. Please request a quote.
Sku SC15-0107_1_G
US-Strem
Get Bulk Quote

Product Information

Product Name
6,6'-(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy) bis(dibenzod,f1,3,2dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS
Brand Name
US-Strem
Product Number
15-0107
CAS
121627-17-6
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
10865829
IUPAC Name
6-2-(2-benzod1,3,2benzodioxaphosphepin-6-yloxy-3-tert-butyl-5-methoxyphenyl)-6-tert-butyl-4-methoxyphenoxybenzod1,3,2benzodioxaphosphepine
InChI Key
WUFGFUAXCBPGOL-UHFFFAOYSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1OP2OC3=CC=CC=C3C4=CC=CC=C4O2)C5=C(C(=CC(=C5)OC)C(C)(C)C)OP6OC7=CC=CC=C7C8=CC=CC=C8O6)OC

Application

Technical Notes:
1.With rhodium forms a highly active catalyst for the hydroformylation of a olefins .
2.The hydroformylation of functionalized a-olefins is highly regios elective. The sterically demanding ligand increases n/iso ratio by reducing rhodium interaction with heteroatom functionality
3. Ligand used in tandem reaction sequences where high n/iso ratio is desired in the hydroformylation step
References:
1.US Patent 47 69498.
2.J. Am. Chem. Soc., 1993, 1 15, 2066.
3.Organometallics, 1995, 14, 3832.
4.J. Mol. Catal. A, 2005, 232, 41.
5.J. Org. Chem. 1995, 60, 7078.
6.J. Org. Chem. 2007, 72, 1871.
7.Chem. Rev.1999, 99, 3329.

References Data Source From Pubchem

Challenges in the Implementation of Technologies for the Sustainable Transformation of Chemical Processes into Industrial Practice
Publication Name: Science for a Better Tomorrow
Publication Date: 2025
DOI: 10.1007/978-3-031-93623-4_9

Highly regioselective synthesis of branched saturated aldehydes by tandem hydroformylation/isomerization/hydrogenation of 1-arylbutadienes
Publication Name: Monatshefte für Chemie - Chemical Monthly
Publication Date: 2024-06-13
DOI: 10.1007/s00706-024-03224-1

Anwendung von Organometallkatalysatoren in der API-Synthese
Publication Name: Organometallik in der Prozesschemie
Publication Date: 2024
DOI: 10.1007/978-3-031-52858-3_4

Influence of Support Structure on Catalytic Performance of Supported Liquid-Phase (SLP) Catalysts in Hydroformylation of 1-Butene
Publication Name: Topics in Catalysis
Publication Date: 2023-03-06
DOI: 10.1007/s11244-023-01792-w

Prospects for using membrane reactors for hydroformylation
Publication Name: Russian Chemical Bulletin
Publication Date: 2023-02
DOI: 10.1007/s11172-023-3807-7