6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS

6,6'-[(3,3'-Di-t-butyl-5,5'-dimethoxy-1,1'-biphenyl-2,2'-diyl)bis(oxy)] bis(dibenzo[d,f][1,3,2]dioxaphosphepin) hemi ethyl acetate adduct, min. 95% BIPHEPHOS

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General Details
Product Number 15-0107
CAS # 121627-17-6
Molecular Formula C46H44O8P2·;0.5EtOAc
Formula Weight 786.78 (830.84)
Physical Properties
Purity min. 95%
Shipping & Stability
Safety Yes

Technical Notes:
1.With rhodium forms a highly active catalyst for the hydroformylation of a olefins .
2.The hydroformylation of functionalized a-olefins is highly regios elective. The sterically demanding ligand increases n/iso ratio by reducing rhodium interaction with heteroatom functionality
3. Ligand used in tandem reaction sequences where high n/iso ratio is desired in the hydroformylation step
References:
1.US Patent 47 69498.
2.J. Am. Chem. Soc., 1993, 1 15, 2066.
3.Organometallics, 1995, 14, 3832.
4.J. Mol. Catal. A, 2005, 232, 41.
5.J. Org. Chem. 1995, 60, 7078.
6.J. Org. Chem. 2007, 72, 1871.
7.Chem. Rev.1999, 99, 3329.