Product Name
2-(Di-t-butylphosphinomethyl)-6-(diethylaminomethyl)pyridine, 98%
Certificate of Analysis (COA)
IUPAC Name
N-6-(ditert-butylphosphanylmethyl)-2-pyridinylmethyl-N-ethylethanamine
InChI Key
MTBWGMDPQBSPGF-UHFFFAOYSA-N
SMILES
CCN(CC)CC1=NC(=CC=C1)CP(C(C)(C)C)C(C)(C)C
Technical Notes:
1. Ligand/Ruthenium catalyst for the direct synthesis of amides from alcohols and primary amines.
2. Ligand/ catalyst for the hydrogenation of esters in high yields under mild pressure and neutral
conditions.
3. Ligand/Ruthenium catalyst for the dehydrogenative coupling of alcohols to form esters in high yields
under neutral conditions.
4. Ligand/Catalytic hydrogenation of dimethyl carbonate, methyl carbamates, and methyl formate, a route to methanol based on co and CO2.
References:
1.Science, 2007, 31 7, 790.
2.Angew. Chem. Int. Ed., 2006, 45, 11 13.
3.J. Am. Chem. Soc., 2005, 127, 12429.
4.J. Am. Chem. Soc., 2005, 127, 10840.
5.Nature, Chem., 2011, 3, 609.
6.Chem. Soc., 2005, 127, 10840
![(R)-[1,1'-Binaphthalene]-2,2'-diylbis[1,1-diphenyl-1,1'-phosphine oxide], 98% (99% ee)|15-0312|94041-16-4](http://www.jk-sci.com/cdn/shop/files/3117e307f3d0924dbdc43a92206364d2_200x200_crop_center.jpg?v=1784770208)
