(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%|15-1363|1372719-93-1

(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno[7,1-de:1',7'-fg][1,3,2]dioxaphosphocin, min. 98%

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Product Information

Product Name
(11aR)-10,11,12,13-Tetrahydro-5-hydroxy-3,7-di-9-phenanthrenyl-5-oxide-diindeno7,1-de:1',7'-fg1,3,2dioxaphosphocin, min. 98%
Brand Name
US-Strem
Product Number
15-1363
CAS
1372719-93-1
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
57341905
IUPAC Name
12-hydroxy-1,10-di(phenanthren-9-yl)-4,5,6,7-tetrahydroiindeno7,1-de:1',7'-fg1,3,2dioxaphosphocine 12-oxide
InChI Key
GMCOBEDKNDREBU-UHFFFAOYSA-N
SMILES
C1CC23CCC4=C2C(=C(C=C4)C5=CC6=CC=CC=C6C7=CC=CC=C75)OP(=O)(OC8=C(C=CC1=C38)C9=CC1=CC=CC=C1C1=CC=CC=C19)O

Application

Technical Notes:
1.Catalytic as ymmetric homo- 1 ,3 -dipolar cycload ditions of azomethine ylides: diastereo and enantios elective s ynthesis ofimidazolidines
2.Enantios elective construction of the biologically significant dibenzo[1 , 4]diazepine scaffold via organocatalytic as ymmetric three component reactions
3.Enantios elective construction of the biologically important cyclopenta[1 , 4]diazepine framework enabled by asymmetric catalysis by chiral spiro-phos phoric acid.
4.Triply hydrogen- bond- directed enantioselective ass embly of pyrrolobenzo-1 ,4-diazine skeletons with quaternary stereocenters.

References

Atroposelective Friedländer Annulation
Publication Name: Science of Synthesis
Publication Date: 2022

Stereoselective Reactions of ortho-Quinone Methide and ortho-Quinone Methide Imines and Their Utility in Natural Product Synthesis
Publication Name: Synthesis
Publication Date: 2018-08-14
DOI: 10.1055/s-0037-1610241