Hexaammineruthenium(III) Chloride (CAS No. 14282-91-8), also known as Ruthenium Hexammine Trichloride or Ru(NH₃)₆Cl₃, is a classic ruthenium coordination complex widely used in electrochemistry, coordination chemistry, analytical chemistry, biosensor development, and materials science. As a stable outer-sphere redox probe, it exhibits rapid and reversible electron-transfer kinetics, making it one of the most widely used redox mediators for electrochemical characterization and sensor evaluation. It is also an important precursor for ruthenium coordination compounds and organometallic research.
| Property | Value |
|---|---|
| Chemical Name | Hexaammineruthenium(III) Chloride |
| Synonyms | Ruthenium Hexammine Trichloride; RuHex; Ru(NH₃)₆Cl₃ |
| CAS Number | 14282-91-8 |
| Molecular Formula | Cl₃H₁₈N₆Ru |
| Molecular Weight | 309.61 g/mol |
| Appearance | Yellow crystalline powder |
| Solubility | Highly soluble in water |
Hexaammineruthenium(III) Chloride possesses several features that make it valuable in electrochemical and coordination chemistry research:
Hexaammineruthenium(III) Chloride is one of the most commonly used outer-sphere redox probes for evaluating electrode performance and electron-transfer kinetics.
Typical applications include:
RuHex is widely employed as a redox indicator in biosensing platforms due to its strong electrostatic interaction with nucleic acids.
Typical applications include:
The compound serves as an important model complex for investigating the structure, bonding, and electron-transfer behavior of transition-metal coordination compounds.
Typical applications include:
RuHex is frequently used as a reference reagent in electroanalytical methods and analytical method development.
Typical applications include:
Used in the development and evaluation of advanced functional materials.
Typical applications include:
| Parameter | Recommended Conditions |
|---|---|
| Solvent | Deionized water or aqueous buffer |
| Storage Temperature | 2–8°C recommended |
| Storage | Store in a tightly sealed container |
| Light Protection | Recommended for long-term storage |
| Experimental Environment | Suitable for aqueous electrochemical systems |
It is primarily used as a redox probe in electrochemical studies, as well as in coordination chemistry, biosensor development, and analytical chemistry.
RuHex undergoes rapid, reversible outer-sphere electron transfer with well-defined electrochemical behavior, making it ideal for evaluating electrode performance and reaction kinetics.
Yes. RuHex is widely employed as an electrochemical indicator for DNA hybridization assays, aptamer sensors, and nucleic acid quantification because it binds electrostatically to the phosphate backbone of nucleic acids.
Yes. It is highly soluble in water, making it suitable for aqueous electrochemical and biological research systems.
Yes. It is frequently used as a reference redox compound for electrochemical instrument calibration, method validation, and analytical method development.
Yes. It serves as a classic ruthenium coordination complex for studying ligand exchange, electron-transfer processes, and transition-metal chemistry.
Store it in a tightly sealed container in a cool, dry place. Refrigerated storage (2–8°C) is recommended for prolonged storage.
Yes. This product is intended for laboratory research and development only and is not intended for pharmaceutical, food, or household applications.
![Cyclopentadienyl[(1,2,3-n)-1-phenyl-2-propenyl]palladium(II), 98%|46-0285|105333-10-6](http://www.jk-sci.com/cdn/shop/files/1f99781d7e132d7e08c4bdc0d971b3e8_200x200_crop_center.jpg?v=1784774374)
