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N-[(1S)-2-(Diphenylphosphino)-1-phenylethyl]-3,5-bis(trifluoromethyl)-benzamide, 95%|15-8514|1853342-57-0

N-[(1S)-2-(Diphenylphosphino)-1-phenylethyl]-3,5-bis(trifluoromethyl)-benzamide, 95%

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Sku SC15-8514_50_MG
US-Strem
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Product Information

Product Name
N-(1S)-2-(Diphenylphosphino)-1-phenylethyl-3,5-bis(trifluoromethyl)-benzamide, 95%
Brand Name
US-Strem
Product Number
15-8514
CAS
1853342-57-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
154726501
IUPAC Name
N-(1S)-2-diphenylphosphanyl-1-phenylethyl-3,5-bis(trifluoromethyl)benzamide
InChI Key
ZFZHBYWMGGPRFC-AREMUKBSSA-N
SMILES
C1=CC=C(C=C1)C@@H(CP(C2=CC=CC=C2)C3=CC=CC=C3)NC(=O)C4=CC(=CC(=C4)C(F)(F)F)C(F)(F)F

Description

Technical Notes:
1.Organocatalyst used in aza-4+2 cycloaddition of N-sulfonyl-1-aza-1 ,3-dienes with vinyl ketones.
2.Catalyst for the enantioselective 3+2 cycloadditions of y-substituted allenoates with ß-perfluoroalkyl enones .
3.Organocatalyst used in effective asymmetric vinylogous Mannich reaction of isatin imines with a,a-dicyanoolefins.
4.Chiral phosphine catalyzed a-functionalization of 2-vinylpyridines via enantioselective cross Rauhut-Currierreaction.
References: 1.Org. Lett. 2017, 19, 1710.
2.Chem. Sci., 2017, 8, 4660.
3.Org. Chem. Front.. 2017, 4, 101.
4.Org Lett. 2018, 20, 1304.

References Data Source From Pubchem

Bifunctional Phosphonium Salts Derived from Chiral Amino Acids
Publication Name: Science of Synthesis
Publication Date: 2022