Product Name
N-(1S)-1-3',5'-Bis(1,1-dimethylethyl)1,1'-biphenyl-2-yl-2-(diphenylphosphino)ethyl-3,5-bis(trifluoromethyl)-benzamide, 95%
Certificate of Analysis (COA)
IUPAC Name
N-(1S)-1-2-(3,5-ditert-butylphenyl)phenyl-2-diphenylphosphanylethyl-3,5-bis(trifluoromethyl)benzamide
InChI Key
YFYKUDPRTXTMTJ-KXQOOQHDSA-N
SMILES
CC(C)(C)C1=CC(=CC(=C1)C2=CC=CC=C2C@@H(CP(C3=CC=CC=C3)C4=CC=CC=C4)NC(=O)C5=CC(=CC(=C5)C(F)(F)F)C(F)(F)F)C(C)(C)C
Technical Notes:
1.Organocatalyst used in aza-4+2 cycloaddition of N-sulfonyl-1-aza-1 ,3-dienes with vinyl ketones.
2.Catalyst for the enantioselective 3+2 cycloadditions of v-substituted allenoates with ß-perfluoroalkyl enones.
3.Phosphine catalyst for difunctionalization of ß-fluoroalkyl a, ß-Enones to generate ß-amino a-diazo carbonyl compounds .
References:
1.Org. L ett.2017, 19, 1710.
2.Chem. Sci., 2017, 8, 4660
3.Angew. Chem. Int. Ed. 2018, 57, 15787.