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Sku SC15-8506_50_MG
US-Strem
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Product Information

Product Name
N-(1S)-1-1,1'-Biphenyl-2-yl-2-(diphenylphosphino)ethyl-3,5-bis(trifluoromethyl)-benzamide, 95%
Brand Name
US-Strem
Product Number
15-8506
CAS
2089424-10-0
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
154703024
IUPAC Name
N-(1S)-2-diphenylphosphanyl-1-(2-phenylphenyl)ethyl-3,5-bis(trifluoromethyl)benzamide
InChI Key
WVVZDTNGVRESKN-JGCGQSQUSA-N
SMILES
C1=CC=C(C=C1)C2=CC=CC=C2C@@H(CP(C3=CC=CC=C3)C4=CC=CC=C4)NC(=O)C5=CC(=CC(=C5)C(F)(F)F)C(F)(F)F

Description

Technical Notes:
1.Organocatalyst used in aza-4+2 cycloaddition of N-sulfonyl-1-aza-1,3-dienes with vinyl ketones.
2.Catalyst for the enantioselective 3+2 cycloadditions of v-substituted allenoates with ß-perfluoroalkyl
enones.
3.Catalyst for asymmetric intermolecular cross Rauhut-Currier reaction of ß-perfluoroalkyl-substituted enones and vinyl ketones.
References:
1.Org. L ett. 2017, 19, 1 710.
2.Chem. Sci., 201 7, 8, 4660.
3.Adv. Synth. Catal. 201 7, 359, 3347 .