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Sku SC15-5990_1_G
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General Details
CAS # 113978-91-9
SMILES
Chemical Purity
Molecular Formula [(C4H9)3PH]BF4ae
Chemical Formula
Formula Weight 290.13
Reaction
Note
Physical Properties
Purity 99%
Density
Melting Point
Boiling Point
Flash Point
Vapor Pressure
Surface Area
Pore Volume
Specific Rotation
Shipping & Stability
Safety Yes
Store Cold
Dry Ice
Alternative Product for Air Shipment
Export Limitations
Pyrophoric
Hygroscopic
Air Sensitive
Light Sensitive
Heat Sensitive
Moisture Sensitive
Odorous Material

Technical Notes:
1. Air-stable, non-pyrophoric precursor of the Tri-n-butylphosphine ligand which is used in a variety of catalytic processes.
2.Catalyst in Baylis-Hillman reactions.
3.Azide reductions.
4.Acylation of alcohols by anhydrides.
5.L igand for formate reduction of allyl carbonates.
6.Synthesis of aromatic nitriles via Pd C-H functionalization.
References:
1Org. L ett., 2001, 3, 4295.
2.Org. L ett., 2003, 5, 3391.
3.J. Am. Chem. Soc., 2007, 129, 15372.