(S)-7,7’-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2’,3,3’-tetrahydro-1,1’-spirobiindane, min. 97% (Sa,S,S)-SpiroBOX

(S)-7,7’-Bis[(4S)-(phenyl)oxazol-2-yl)]-2,2’,3,3’-tetrahydro-1,1’-spirobiindane, min. 97% (Sa,S,S)-SpiroBOX

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Sku SC07-5195_100_MG
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General Details
Product Number 07-5195
CAS # 940880-69-3
Molecular Formula C35H30N2O2
Formula Weight 510.62
Physical Properties
Purity min. 97%
Shipping & Stability
Safety Yes

Technical Notes:
1.Chiral ligands for copper- catalyzed asymmetric insertions of carbenoids into N- H bond of anilines.
2.Chiral ligands for copper or palladium-catalyzed asymmetric insertions of carbenoids into o -H bond of phenols.
3.Chiral ligands for copper or iron-catalyzed asymmetric insertions of carbenoids into o H bond of water.
4.Chiral ligands for copper-catalyzed asymmetric insertions of carbenoids into S-H bonds of arylmethylene mercaptans.
References:
1.J. Am. Chem. Soc. 2007. 129, 5834 5835 2.J.Am. Chem.Soc.2012, 134 436442.
3.J. Am. Chem. Soc. 2007. 129, 12616 -12617.
4.Angew. Chem., Int. Ed.. 2013, 52, 2555. 5.Angew. Chem., Int. Ed., 2014, 53, 2978
6.Angew. Chem. Int. Ed., 2008, 47, 932 -934. 7.Nature Chemistry, 2010, 2, 546 551.
8.Chem. Commun.. 2009, 5362.