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Sku SC07-5194_100_MG
US-Strem
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Product Information

Product Name
(R)-7,7’-Bis(4S)-(phenyl)oxazol-2-yl)-2,2’,3,3’-tetrahydro-1,1’-spirobiindane, min. 97% (Ra,S,S)-SpiroBOX
Brand Name
US-Strem
Product Number
07-5194
CAS
890090-21-8
Certificate of Analysis (COA)​
COA not found

General Information

PubChem CID
16655517
IUPAC Name
(4S)-4-phenyl-2-4'-(4S)-4-phenyl-4,5-dihydro-1,3-oxazol-2-yl-3,3'-spirobi1,2-dihydroindene-4-yl-4,5-dihydro-1,3-oxazole
InChI Key
OUEHZICAZAUZFM-NYHVVPQYSA-N
SMILES
C1CC2(CCC3=C2C(=CC=C3)C4=NC@H(CO4)C5=CC=CC=C5)C6=C1C=CC=C6C7=NC@H(CO7)C8=CC=CC=C8

Description

Technical Notes:
1. Fe-catalyzed C-H functionalization of indoles
2.Enantioselective Cu-catalyzed, intramolecular phenolic O-H bond inse rtion
3.Cu-catalyzed, enantioselective allylic oxidation of acylic olefins
4.A highly efficient and e nantioselective c-B bond forming reaction with amine -borane and phosphine-borane adducts
5.Enantioselective Fe-catalyzed intramolecular cyclopropanation reactions
6.Highly enantioselective Cu- and Fe-catalyzed intramolecular cyclopropanation of indoles

References Data Source From Pubchem

Insertion and Cyclopropanation Reactions with α-Aryl α-Diazo Esters

Publication Name: Science of Synthesis
Publication Date: 2023

Synthesis of α-Boryl Esters by Copper-Catalyzed B—H Bond Insertion Reactions

Publication Name: Science of Synthesis
Publication Date: 2021

Asymmetric Copper- or Iron-Catalyzed Intramolecular Cyclopropanation

Publication Name: Synfacts
Publication Date: 2017-07-18
DOI: 10.1055/s-0036-1590667

Copper-Catalyzed Asymmetric Synthesis of 2-Carboxytetrahydroquinolines

Publication Name: Synfacts
Publication Date: 2016-10-18
DOI: 10.1055/s-0036-1589350

Enantioselective Iron-Catalyzed Intramolecular Cyclopropanation Reactions

Publication Name: Science of Synthesis
Publication Date: 2016